Cononsolvency of thermoresponsive polymers: where we are now and where we are going
Cononsolvency is an intriguing phenomenon where a polymer collapses in a mixture of
good solvents. This cosolvent-induced modulation of the polymer solubility has been …
good solvents. This cosolvent-induced modulation of the polymer solubility has been …
Thermoresponsive Polymers under Pressure with a Focus on Poly(N-isopropylacrylamide) (PNIPAM)
CM Papadakis, BJ Niebuur, A Schulte - Langmuir, 2023 - ACS Publications
Pressure is a key variable in the phase behavior of responsive polymers, both for
applications and from a fundamental point of view. In this feature article, we review recent …
applications and from a fundamental point of view. In this feature article, we review recent …
Effect of Temperature on the Cononsolvency of Poly(N-isopropylacrylamide) (PNIPAM) in Aqueous 1-Propanol
HA Pérez-Ramírez, C Haro-Pérez… - ACS Applied Polymer …, 2019 - ACS Publications
The wide range of applications of poly (N-isopropylacrylamide)(PNIPAM) is based on the
temperature dependence of its coil-to-globule transition, which strongly relies on the solvent …
temperature dependence of its coil-to-globule transition, which strongly relies on the solvent …
Flory-type theories of polymer chains under different external stimuli
YA Budkov, MG Kiselev - Journal of Physics: Condensed Matter, 2017 - iopscience.iop.org
In this Review, we present a critical analysis of various applications of the Flory-type theories
to a theoretical description of the conformational behavior of single polymer chains in dilute …
to a theoretical description of the conformational behavior of single polymer chains in dilute …
Tuning the collapse transition of weakly charged polymers by ion-specific screening and adsorption
R Chudoba, J Heyda, J Dzubiella - Soft matter, 2018 - pubs.rsc.org
The experimentally observed swelling and collapse response of weakly charged polymers
to the addition of specific salts displays quite convoluted behavior that is not easy to …
to the addition of specific salts displays quite convoluted behavior that is not easy to …
Effects of enhanced flexibility and pore size distribution on adsorption-induced deformation of mesoporous materials
AL Kolesnikov, N Georgi, YA Budkov, J Möllmer… - Langmuir, 2018 - ACS Publications
Here, we present a new model of adsorption-induced deformation of mesoporous solids.
The model is based on a simplified version of local density functional theory in the …
The model is based on a simplified version of local density functional theory in the …
Conformation Transition of a Homopolymer Chain in Binary Mixed Solvents
On the basis of a minimal lattice model, we apply the Wang–Landau Monte Carlo (MC)
algorithm and a Flory-type mean-field theory to investigate the conformation of a …
algorithm and a Flory-type mean-field theory to investigate the conformation of a …
Models of the conformational behavior of polymers in mixed solvents
YA Budkov, AL Kolesnikov - Polymer Science, Series C, 2018 - Springer
Theoretical models of the conformational behavior of flexible polymer chains in mixed
solvents enunciated in the world literature during the last decade are critically reviewed …
solvents enunciated in the world literature during the last decade are critically reviewed …
A poromechanical model for sorption hysteresis in nanoporous polymers
Sorption hysteresis in nanoporous polymer is an intriguing phenomenon that involves
coupling between sorption and deformation. Based on the mechanism revealed at the …
coupling between sorption and deformation. Based on the mechanism revealed at the …
Pressure Dependence of the Cononsolvency Effect in Aqueous Poly(N-isopropylacrylamide) Solutions: A SANS Study
BJ Niebuur, CH Ko, X Zhang, KL Claude… - …, 2020 - ACS Publications
The cononsolvency effect of poly (N-isopropylacrylamide)(PNIPAM) in a mixture of water
and methanol is investigated at variable temperatures (∼ 20–50° C) and pressures (0.1 …
and methanol is investigated at variable temperatures (∼ 20–50° C) and pressures (0.1 …