Nickel catalyzed olefin oligomerization and dimerization

H Olivier-Bourbigou, PAR Breuil, L Magna… - Chemical …, 2020 - ACS Publications
Brought to life more than half a century ago and successfully applied for high-value
petrochemical intermediates production, nickel-catalyzed olefin oligomerization is still a very …

Bridging the Gap between Industrial and Well‐Defined Supported Catalysts

C Copéret, F Allouche, KW Chan… - Angewandte Chemie …, 2018 - Wiley Online Library
Many industrial catalysts contain isolated metal sites on the surface of oxide supports.
Although such catalysts have been used in a broad range of processes for more than 40 …

Nickel-based solid catalysts for ethylene oligomerization–a review

A Finiels, F Fajula, V Hulea - Catalysis Science & Technology, 2014 - pubs.rsc.org
Ni-based inorganic porous materials are the most important heterogeneous catalysts for
ethylene oligomerization. In spite of extensive research carried out in previous decades on …

[图书][B] Molecular spectroscopy of oxide catalyst surfaces

AA Davydov, NT Sheppard - 2003 - lehigh.edu
The surface chemistry of oxide surfaces has been receiving greater fundamental interest in
recent years because of the expanding technological applications of oxide materials (eg …

Nature of active nickel sites and initiation mechanism for ethylene oligomerization on heterogeneous Ni-beta catalysts

S Moussa, P Concepción, MA Arribas, A Martínez - Acs Catalysis, 2018 - ACS Publications
Higher olefins produced via ethylene oligomerization are versatile commodity chemicals
serving a vast range of industries with large global economic impact. Nickel aluminosilicates …

New bifunctional Ni–H-Beta catalysts for the heterogeneous oligomerization of ethylene

A Martínez, MA Arribas, P Concepción… - Applied Catalysis A …, 2013 - Elsevier
The development of sustainable active and stable heterogeneous catalysts for the
oligomerization of ethylene to replace the unfriendly homogenous systems based on …

Ni-exchanged AlMCM-41—An efficient bifunctional catalyst for ethylene oligomerization

V Hulea, F Fajula - Journal of Catalysis, 2004 - Elsevier
A series of Ni-exchanged AlMCM-41 catalysts with carefully controlled concentrations of
metallic and acidic sites was prepared, characterized, and tested in ethylene oligomerization …

Toward platform chemicals from bio-based ethylene: heterogeneous catalysts and processes

V Hulea - ACS Catalysis, 2018 - ACS Publications
With stricter ecological regulation and reduction of fossil feedstock, the research works have
been oriented to renewable resources. Various bio-based molecules have been proposed …

Evidence for the coordination–insertion mechanism of ethene dimerization at nickel cations exchanged onto beta molecular sieves

R Joshi, G Zhang, JT Miller, R Gounder - Acs Catalysis, 2018 - ACS Publications
The mechanistic origin of alkene dimerization on Ni sites supported on aluminosilicates has
been ascribed to both coordination–insertion (ie, Cossee-Arlman) and metallacycle-based …

Catalytic oligomerization of ethylene over Ni-containing dealuminated Y zeolites

M Lallemand, A Finiels, F Fajula, V Hulea - Applied Catalysis A: General, 2006 - Elsevier
Ni-containing dealuminated Y zeolites with different Si/Al ratios were prepared,
characterized and tested in the ethylene oligomerization reaction, performed in slurry semi …