Metal‐Modified Nucleic Acids: Metal‐Mediated Base Pairs, Triples, and Tetrads

S Naskar, R Guha, J Mueller - … Chemie International Edition, 2020 - Wiley Online Library
The incorporation of metal ions into nucleic acids by means of metal‐mediated base pairs
represents a promising and prominent strategy for the site‐specific decoration of these self …

Nucleic acid duplexes with metal-mediated base pairs and their structures

J Müller - Coordination Chemistry Reviews, 2019 - Elsevier
Metal-mediated base pairs represent a topical area of research at the border of bioinorganic
chemistry, supramolecular coordination chemistry and DNA nanotechnology. In a metal …

Metal‐Mediated Base Pairs: From Characterization to Application

B Jash, J Müller - Chemistry–A European Journal, 2017 - Wiley Online Library
The investigation of metal‐mediated base pairs and the development of their applications
represent a prominent area of research at the border of bioinorganic chemistry and …

Addressing the properties of “Metallo-DNA” with a Ag (i)-mediated supramolecular duplex

L Mistry, O El-Zubir, G Dura, W Clegg, PG Waddell… - Chemical …, 2019 - pubs.rsc.org
The silver-nucleoside complex [Ag (I)-(N3-cytidine) 2], 1, self-assembles to form a
supramolecular metal-mediated base-pair array highly analogous to those seen in metallo …

Stable Copper (I)‐Mediated Base Pairing in DNA

B Jash, J Müller - Angewandte Chemie International Edition, 2018 - Wiley Online Library
A GNA (glycol nucleic acid) functionalized nucleoside analogue containing the artificial
nucleobase 1H‐imidazo [4, 5‐f][1, 10] phenanthroline (P) was used to form a copper (I) …

Metal-mediated base pairing in DNA involving the artificial nucleobase imidazole-4-carboxylate

N Sandmann, D Defayay, A Hepp, J Müller - Journal of Inorganic …, 2019 - Elsevier
The use of imidazole-4-carboxylate (X) as an artificial nucleobase in metal-mediated base
pairing is reported. Towards this end, the corresponding deoxyribonucleoside was …

Electrochemical detection of 25-hydroxyvitamin D3 using an oligonucleotide aptasensor

S Yin, Y Li, MN Hossain, C Sun, HB Kraatz - Sensors and Actuators B …, 2021 - Elsevier
Vitamin D deficiency remains a serious health issue in many developing countries and
regions with a deficiency of sunlight. And although the demand for vitamin D testing has …

Chiral‐at‐Metal Silver‐Mediated Base Pairs: Metal‐Centred Chirality versus DNA Helical Chirality

N Lefringhausen, V Seiffert, C Erbacher… - … A European Journal, 2023 - Wiley Online Library
When covalently incorporating ligands capable of forming chiral metal complexes into a
DNA oligonucleotide duplex, an enantiospecific formation of metal‐mediated base pairs is …

Incorporation of a metal-mediated base pair into an ATP aptamer–using silver (I) ions to modulate aptamer function

MH Heddinga, J Müller - Beilstein Journal of Organic …, 2020 - beilstein-journals.org
For the first time, a metal-mediated base pair has been used to modulate the affinity of an
aptamer towards its target. In particular, two artificial imidazole 2'-deoxyribonucleosides (Im) …

Repeated and Folded DNA Sequences and Their Modular Ag106+ Cluster

JT Petty, M Ganguly, IJ Rankine… - The Journal of …, 2018 - ACS Publications
Molecular silver clusters are optical chromophores, and species with distinct spectra form
with DNA strands. One such hybrid chromophore is a violet cluster bound to repeated C2X …