Synergistic catalysis, a type of plural catalysis which utilizes at least two different catalysts to
enable a reaction between two separately activated substrates, has unlocked a plethora of …

This review covers diastereo-and enantiodivergent catalyzed reactions in acyclic and cyclic
systems using metal complexes or organocatalysts. Among them, nucleophilic addition to …

Multicatalysis is an emerging field targeting the development of efficient catalytic
transformations to quickly convert relatively simple starting materials into more complex …

The activation of a substrate by a chiral catalyst is now regarded as one of the most powerful
strategies that can be employed in the art of asymmetric synthesis. 1 The development of …

One-pot reactions elaborated around transition metal-catalyzed isomerization of alkenes not
only offer the inherent advantages of atom-, step-and redox-economy but also enable the …

N‐Heterocyclic carbene (NHC) catalysis has emerged as a powerful stratagem in organic
synthesis to construct complex molecules primarily by polarity reversal (umpolung) …

Transition-metal-catalyzed reactions have been studied since the very beginning of the past
century and represent a great success in organic chemistry, along with the birth and growth …

Charged intermediates and reagents are ubiquitous in organic transformations. The
interaction of these ionic species with chiral neutral, anionic, or cationic small molecules has …

Supramolecular catalysis is a rapidly expanding discipline which has benefited from the
development of both homogeneous catalysis and supramolecular chemistry. The properties …

The photoredox activation of organic substrates with visible light is a powerful methodology
that generates reactive radical species under very mild conditions. When combined with …