Carbon–Carbon Bond Cleavage for Late-Stage Functionalization
YF Liang, M Bilal, LY Tang, TZ Wang, YQ Guan… - Chemical …, 2023 - ACS Publications
Late-stage functionalization (LSF) introduces functional group or structural modification at
the final stage of the synthesis of natural products, drugs, and complex compounds. It is …
the final stage of the synthesis of natural products, drugs, and complex compounds. It is …
Benzo-fused-ring toolbox based on palladium/norbornene cooperative catalysis: methodology development and applications in natural product synthesis
HG Cheng, S Jia, Q Zhou - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Benzo-fused skeletons are ubiquitous in agrochemicals, medicines, natural
products, catalysts, and other organic function materials. The assembly of these skeletons in …
products, catalysts, and other organic function materials. The assembly of these skeletons in …
Palladium (II)‐Initiated Catellani‐Type Reactions
HG Cheng, S Chen, R Chen, Q Zhou - Angewandte Chemie, 2019 - Wiley Online Library
The Catellani reaction is known as a powerful strategy for the expeditious synthesis of highly
substituted arenes and benzo‐fused rings, which are usually difficult to access through …
substituted arenes and benzo‐fused rings, which are usually difficult to access through …
Structurally modified norbornenes: a key factor to modulate reaction selectivity in the palladium/norbornene cooperative catalysis
Palladium/norbornene (Pd/NBE) cooperative catalysis has received enormous attention and
found numerous synthetic applications in the past two decades. Considering the critical …
found numerous synthetic applications in the past two decades. Considering the critical …
Catalytic enantioselective α-arylation of carbonyl enolates and related compounds
YJ Hao, XS Hu, Y Zhou, J Zhou, JS Yu - ACS Catalysis, 2019 - ACS Publications
Optically active α-arylation carbonyl units are widely present in a wide variety of drugs,
bioactive natural products, and valuable pharmacologically active molecules. Catalytic …
bioactive natural products, and valuable pharmacologically active molecules. Catalytic …
Recent progress on Catellani reaction
Z Chen, F Zhang - Tetrahedron, 2023 - Elsevier
The Catellani reaction is a palladium-catalyzed hydrocarbon-activated multicomponent
tandem reaction involving an aryl halide, an electrophilic coupling reagent and a terminating …
tandem reaction involving an aryl halide, an electrophilic coupling reagent and a terminating …
Modular dual-tasked C–H methylation via the Catellani strategy
Q Gao, Y Shang, F Song, J Ye, ZS Liu, L Li… - Journal of the …, 2019 - ACS Publications
We report a dual-tasked methylation that is based on cooperative palladium/norbornene
catalysis. Readily available (hetero) aryl halides (39 iodides and 4 bromides) and …
catalysis. Readily available (hetero) aryl halides (39 iodides and 4 bromides) and …
Catellani reaction: an enabling technology for vicinal functionalization of aryl halides by palladium (0)/norbornene cooperative catalysis
S Dong, X Luan - Chinese Journal of Chemistry, 2021 - Wiley Online Library
The Catellani reaction, originally discovered by Catellani in 1997, and further developed by
Catellani, Lautens and others, has emerged as a powerful strategy for the synthesis of …
Catellani, Lautens and others, has emerged as a powerful strategy for the synthesis of …
Site-selective 1, 1-difunctionalization of unactivated alkenes enabled by cationic palladium catalysis
A palladium (II)-catalyzed 1, 1-difunctionalization of unactivated terminal and internal
alkenes via addition of two nucleophiles was developed using a cationic palladium (II) …
alkenes via addition of two nucleophiles was developed using a cationic palladium (II) …