This review discusses recent advances in the chemistry of saturated boronic acids,
boronates, and trifluoroborates. Applications of the title compounds in the design of boron …

INTRODUCTION The boronic acid is a functional group of enormous utility in materials
science, chemosensor development, and drug discovery. In medicinal chemistry, boronic …

We present a new, unified approach for the transformation of benzylic and allylic alcohols,
aldehydes, and ketones into boronic esters under electroreductive conditions. Key to our …

A strategy that facilitates the construction of a wide variety of trisubstituted stereocenters
through a catalytically accessed common chiral intermediate could prove highly enabling for …

We report herein a new method for the photoredox activation of boronic esters. Using these
reagents, an efficient and high‐throughput continuous flow process was developed to …

Introducing the novel concept of amino radical transfer (ART) enables the use of easily
accessible and commercially available alkyl boronic esters as cross-coupling partners for …

Organoboron compounds are powerful reagents in synthetic chemistry. Carbonyl and
carboxyl compounds are widely accessible chemical feedstocks. The synthesis of …

We report the first enantioselective Rh-catalyzed Markovnikov hydroboration of unactivated
terminal alkenes. Using a novel sp2–sp3 hybridized diboron reagent and water as a proton …

In planning organic syntheses, disconnections are most often made adjacent to functional
groups, which assist in C–C bond formation. For molecules devoid of obvious functional …

Summary of main observation and conclusion A regioselective double 1, 1‐hydrosilylation of
terminal aliphatic alkynes with primary silanes catalyzed by one cobalt catalyst has been …