Site-predictable and chemoselective C–H bond functionalization reactions offer synthetically
powerful strategies for the step-economic diversification of both feedstock and fine …

Transition metal–catalyzed C─ H bond activation and borylation is a powerful synthetic
method that offers versatile synthetic transformation from organoboron compounds to …

Borylations of inert carbon–hydrogen bonds are highly useful for transforming feedstock
chemicals into versatile organoboron reagents. Catalysis of these reactions has historically …

BN-embedded nonacene, tridecacene, and heptadecacene frameworks were constructed
using one-shot quadruple, sextuple, and octuple borylation reactions, respectively. The key …

Pd (II)-catalyzed nondirected C–H functionalization of heteroarenes is a significant
challenge for the following reasons: poor reactivity of electron-deficient heterocycles and the …

Remote meta selective C–H functionalization of aromatic compounds remains a challenging
problem in chemical synthesis. Here, we report an iridium catalyst bearing a bidentate …

Transition metal‐catalyzed enantioselective C− H activation of prochiral sulfoximines for non‐
annulated products remains a formidable challenge. We herein report iridium‐catalyzed …

Transition metal‐catalyzed site‐and stereoselective C− H activation of strained (hetero)
cycloalkanes remains a formidable challenge. We herein report a carbamate‐directed …

Reported here is an efficient and simple ether‐directed iridium‐catalyzed enantioselective C
(sp3)− H borylation of cyclopropanes. Various functional groups were well‐tolerated …

Iridium-catalyzed C–H activation and borylation has become as a powerful synthetic tool in
the past few decades because of the widespread applicability and versatility of organoboron …