An unusual O/F ordered d0 transition metal fluoroantimonite, namely, K2SbMoO2F7, has
been created by the cationic size effect of alkali metals. It features the largest birefringence …

Developing high-performance infrared (IR) nonlinear optical (NLO) materials is essential for
modern laser technology, but challenging due to the competition of the NLO coefficient and …

Chirality and polarity are the two most important and representative symmetry‐dependent
properties. For polar structures, all the twofold axes perpendicular to the principal axis of …

Considerable effort has been invested in the development of non‐centrosymmetric (NCS)
inorganic solids for ferroelectricity‐, piezoelectricity‐and, particularly, optical nonlinearity …

The synthesis and characterization of three new hybrid metal halide hydrates in which mer-
[CrIIICl3 (H2O) 3] 0 cocrystallizes alongside α-methylbenzylammonium chloride are …

The d0 transition metal oxides are the most commonly used nonlinear optical (NLO)
materials in the visible light region; however, their limited band gaps seriously hinder their …

The design of both molecular and non-molecular solid materials with specific properties
fundamentally relies on the controlled synthesis of crystals with desired functional groups …

The chirality of metal‐organic cages holds enormous potential for novel applications in
diverse fields, while it is relatively rare to employ such asymmetric units for the construction …