Porous materials for hydrogen storage

Z Chen, KO Kirlikovali, KB Idrees, MC Wasson… - Chem, 2022 - cell.com
The development of efficient storage materials for hydrogen is important for the viable
implementation of hydrogen-powered fuel-cell automobiles. In this review, we summarize …

A historical overview of the activation and porosity of metal–organic frameworks

X Zhang, Z Chen, X Liu, SL Hanna, X Wang… - Chemical Society …, 2020 - pubs.rsc.org
Since the first reports of metal–organic frameworks (MOFs), this unique class of crystalline,
porous materials has garnered increasing attention in a wide variety of applications such as …

25 years of reticular chemistry

R Freund, S Canossa, SM Cohen… - Angewandte Chemie …, 2021 - Wiley Online Library
At its core, reticular chemistry has translated the precision and expertise of organic and
inorganic synthesis to the solid state. While initial excitement over metal–organic …

A reticular chemistry guide for the design of periodic solids

H Jiang, D Alezi, M Eddaoudi - Nature Reviews Materials, 2021 - nature.com
Reticular chemistry—the linking of well-defined molecular building blocks by strong bonds
into crystalline extended frameworks—has enabled the synthesis of diverse metal–organic …

Machine learning the quantum-chemical properties of metal–organic frameworks for accelerated materials discovery

AS Rosen, SM Iyer, D Ray, Z Yao, A Aspuru-Guzik… - Matter, 2021 - cell.com
The modular nature of metal–organic frameworks (MOFs) enables synthetic control over
their physical and chemical properties, but it can be difficult to know which MOFs would be …

Stable metal–organic frameworks: design, synthesis, and applications

S Yuan, L Feng, K Wang, J Pang, M Bosch… - Advanced …, 2018 - Wiley Online Library
Metal–organic frameworks (MOFs) are an emerging class of porous materials with potential
applications in gas storage, separations, catalysis, and chemical sensing. Despite numerous …

Secondary building units as the turning point in the development of the reticular chemistry of MOFs

MJ Kalmutzki, N Hanikel, OM Yaghi - Science advances, 2018 - science.org
The secondary building unit (SBU) approach was a turning point in the discovery of
permanently porous metal-organic frameworks (MOFs) and in launching the field of reticular …

Metal–organic frameworks based on multicarboxylate linkers

H Ghasempour, KY Wang, JA Powell… - Coordination Chemistry …, 2021 - Elsevier
When designing metal–organic frameworks (MOFs), linker design is one of the most
important factors in constructing a wide variety of structures. Judicious choice of linker size …

MOF Crystal Chemistry Paving the Way to Gas Storage Needs: Aluminum-Based soc-MOF for CH4, O2, and CO2 Storage

D Alezi, Y Belmabkhout, M Suyetin… - Journal of the …, 2015 - ACS Publications
The molecular building block approach was employed effectively to construct a series of
novel isoreticular, highly porous and stable, aluminum-based metal–organic frameworks …

Tuning the structure and function of metal–organic frameworks via linker design

W Lu, Z Wei, ZY Gu, TF Liu, J Park, J Park… - Chemical Society …, 2014 - pubs.rsc.org
Metal–organic frameworks (MOFs) are constructed from metal ions/clusters coordinated by
organic linkers (or bridging-ligands). The hallmark of MOFs is their permanent porosity …