Stabilization mechanism and chemical demulsification of water-in-oil and oil-in-water emulsions in petroleum industry: A review

D Wang, D Yang, C Huang, Y Huang, D Yang, H Zhang… - Fuel, 2021 - Elsevier
Emulsions frequently encountered in petroleum production, include water-in-oil (W/O)
emulsions, oil-in-water (O/W) emulsions, and water-in-oil-in-water (W/O/W) emulsions, which …

The asphaltenes

OC Mullins - Annual review of analytical chemistry, 2011 - annualreviews.org
Asphaltenes, the most aromatic of the heaviest components of crude oil, are critical to all
aspects of petroleum utilization, including reservoir characterization, production …

Advances in asphaltene science and the Yen–Mullins model

OC Mullins, H Sabbah, J Eyssautier… - Energy & …, 2012 - ACS Publications
The Yen–Mullins model, also known as the modified Yen model, specifies the predominant
molecular and colloidal structure of asphaltenes in crude oils and laboratory solvents and …

Overview of asphaltene nanostructures and thermodynamic applications

B Schuler, Y Zhang, F Liu, AE Pomerantz… - Energy & …, 2020 - ACS Publications
Previously, asphaltene science had been hindered by many significant uncertainties
regarding molecular weight, molecular structure, and nanocolloidal characteristics in …

Adsorption kinetics of asphaltenes at oil/water interface: Effects of concentration and temperature

S Zhang, L Zhang, X Lu, C Shi, T Tang, X Wang… - Fuel, 2018 - Elsevier
Asphaltenes are the heaviest components in crude oil. It is generally believed that
asphaltenes adsorbed at oil/water interface can form a protective layer to stabilize the water …

Asphaltene subfractions responsible for stabilizing water-in-crude oil emulsions. Part 1: interfacial behaviors

F Yang, P Tchoukov, E Pensini, T Dabros… - Energy & …, 2014 - ACS Publications
The asphaltene fraction of crude oil is commonly considered to be responsible for the
formation of highly undesirable, stable water-in-crude oil emulsions and rag layers. We …

Asphaltene aggregation and impact of alkylphenols

L Goual, M Sedghi, X Wang, Z Zhu - Langmuir, 2014 - ACS Publications
The main objective of this study was to provide novel insights into the mechanism of
asphaltene aggregation in toluene/heptane (Heptol) solutions and the effect of alkylphenols …

Heavy petroleum composition. 3. Asphaltene aggregation

AM McKenna, LJ Donald, JE Fitzsimmons, P Juyal… - Energy & …, 2013 - ACS Publications
Molecular characterization of asphaltenes by conventional analytical techniques is a
challenge because of their compositional complexity, high heteroatom content, and …

Clusters of asphaltene nanoaggregates observed in oilfield reservoirs

OC Mullins, DJ Seifert, JY Zuo, M Zeybek - Energy & Fuels, 2013 - ACS Publications
Many studies have indicated that asphaltenes have two hierarchical nanocolloidal species,
the nanoaggregate and the cluster of nanoaggregates. These two species, along with the …

Heavy petroleum composition. 4. Asphaltene compositional space

AM McKenna, AG Marshall, RP Rodgers - Energy & Fuels, 2013 - ACS Publications
Asphaltenes and maltenes are defined operationally by solubility (in, eg, heptane).
Asphaltenes self-associate in solution and form putative nanoaggregates composed of …