Electrochemistry grants direct access to reactive intermediates (radicals and ions) in a
controlled fashion toward selective organic transformations. This feature has been …

Currently, the construction of new carbon–carbon bonds and value-added structures in an
atom-and step economical manner has become a continuous pursuit in the synthetic …

Alkynes represent a family of pivotal and sustainable feedstocks for various industries such
as pharmaceuticals, agrochemicals, and materials, and they are widely used as important …

We synthesized tetrasubstituted olefins regioselectively and stereoselectively from ynamides
and internal alkynes with sulfonyl iodides under blue LEDs in few minutes. The key features …

An unprecedented copper-promoted radical-mediated alkenyl C (sp2)–H carbonylation of
alkenes with polyhaloalkanes for divergently producing α, β-unsaturated esters and …

Highly functionalized N-substituted arylamines are the core structural motifs of numerous
biologically active molecules, agrochemicals, and functional materials. Classically, using …

The highly toxic and flammable nature of CO lead to high handling demand for its use and
storage, undoubtedly constricting its further academic exploration for carbonylative reactions …

We herein report an efficient photoredox radical cyclization reaction of o-vinylaryl
isocyanides with acyl chlorides to access a wide range of 2, 4-disubstituted quinolines …

Here we report a palladium‐catalysed difunctionalisation of unsaturated C− C bonds with
acid chlorides. Formally, the C− COCl bond of an acid chloride is cleaved and added, with …

Hydrocyanation reactions enable access to synthetically valuable nitriles from readily
available alkene precursors. However, hydrocyanation reactions using hydrogen cyanide …