Synergistic dual transition metal catalysis

UB Kim, DJ Jung, HJ Jeon, K Rathwell… - Chemical Reviews, 2020 - ACS Publications
Synergistic catalysis, a type of plural catalysis which utilizes at least two different catalysts to
enable a reaction between two separately activated substrates, has unlocked a plethora of …

Recent developments in nickel-catalyzed intermolecular dicarbofunctionalization of alkenes

J Derosa, O Apolinar, T Kang, VT Tran, KM Engle - Chemical Science, 2020 - pubs.rsc.org
Nickel-catalyzed three-component alkene difunctionalization has rapidly emerged as a
powerful tool for forging two C–C bonds in a single reaction. Building upon the powerful …

CuH-catalyzed olefin functionalization: from hydroamination to carbonyl addition

RY Liu, SL Buchwald - Accounts of chemical research, 2020 - ACS Publications
Conspectus In organic synthesis, ligand-modified copper (I) hydride (CuH) complexes have
become well-known reagents and catalysts for selective reduction, particularly toward …

Copper-catalyzed borylative difunctionalization of π-systems

A Whyte, A Torelli, B Mirabi, A Zhang, M Lautens - ACS Catalysis, 2020 - ACS Publications
Organoboronates represent a cornerstone functional group in modern synthesis owing to
their unique reactivity and divergent synthetic capability. Copper catalysis has become one …

Diboron (4) compounds: from structural curiosity to synthetic workhorse

EC Neeve, SJ Geier, IAI Mkhalid, SA Westcott… - Chemical …, 2016 - ACS Publications
Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

Recent developments in organoboron chemistry: old dogs, new tricks

JWB Fyfe, AJB Watson - Chem, 2017 - cell.com
Organoboron reagents are one of the most widely studied and applied classes of reagent
throughout organic synthesis and catalysis. Not only are these reagents integral to many of …

N-heterocyclic carbene complexes of copper, nickel, and cobalt

AA Danopoulos, T Simler, P Braunstein - Chemical reviews, 2019 - ACS Publications
The emergence of N-heterocyclic carbenes as ligands across the Periodic Table had an
impact on various aspects of the coordination, organometallic, and catalytic chemistry of the …

Copper-boryl mediated organic synthesis

D Hemming, R Fritzemeier, SA Westcott… - Chemical Society …, 2018 - pubs.rsc.org
Organoboron compounds are valuable synthetic intermediates that find application in a
diverse variety of processes including both C–X and C–C bond-forming transformations …

Bimetallic catalysis for C–C and C–X coupling reactions

DR Pye, NP Mankad - Chemical Science, 2017 - pubs.rsc.org
Bimetallic catalysis represents an alternative paradigm for coupling chemistry that
complements the more traditional single-site catalysis approach. In this perspective, recent …

Multimetallic-catalyzed C–C bond-forming reactions: from serendipity to strategy

LKG Ackerman-Biegasiewicz… - Journal of the …, 2023 - ACS Publications
The use of two or more metal catalysts in a reaction is a powerful synthetic strategy to access
complex targets efficiently and selectively from simple starting materials. While capable of …