Bidentate organophosphorus ligands formed via P–N bond formation: synthesis and coordination chemistry

TQ Ly, JD Woollins - Coordination chemistry reviews, 1998 - Elsevier
This article outlines two related bidentate organophosphorus ligand systems prepared by
phosphorus–nitrogen (P–N) bond formation—R2 (E) PNHPR2, RC (E) NHPR2 (E= O, S, or …

Bis (diphenylphosphino) amine and related chemistry

P Bhattacharyya, JD Woollins - Polyhedron, 1995 - Elsevier
Throughout inorganic and organometallic chemistry few ligands have been as widely
employed as tertiary mono-and diphosphines]~ It is still perhaps true to say that the most …

Selenium-77 nuclear magnetic resonance spectroscopy

H Duddeck - Progress in Nuclear Magnetic Resonance …, 1995 - Elsevier
2.2. Referencing 2.3. Medium effects 2.3. 1. Concentration dependence 2.3. 2. Solvent
dependence 2.3. 3. Temperature dependence 2.3. 4. pH dependence 2.4. Isotope effects …

Structural diversity in coordination chemistry of tridentate and tetradentate polyphosphines of Group 6 to 10 transition metal complexes

JC Hierso, R Amardeil, E Bentabet, R Broussier… - Coordination chemistry …, 2003 - Elsevier
Tridentate and tetradentate polyphosphines offer a huge variety of coordination modes to
transition metals which lead, depending on the metal, to very different structural features in …

MoS 2 supported single platinum atoms and their superior catalytic activity for CO oxidation: a density functional theory study

C Du, H Lin, B Lin, Z Ma, T Hou, J Tang… - Journal of Materials …, 2015 - pubs.rsc.org
Late transition metals, such as Rh, Ir, Pd and Pt, have a strong tendency to form a square-
planar 16-electron complex. Although this feature has been widely used in organometallics …

Palladium(II) and Platinum(II) Complexes of the Heterodifunctional Ligand Ph2PNHP(O)Ph2

P Bhattacharyya, AMZ Slawin, MB Smith… - Inorganic …, 1996 - ACS Publications
The noncomplexed ligand Ph2PNHP (O) Ph2 (HL) has been prepared, for the first time, from
Ph2PNHPPh2 (dppa) and H2O2 in moderate yield. On further treatment with H2O2 the …

Combined Experimental and Theoretical Study of Bis(diphenylphosphino)(N-thioether)amine-Type Ligands in Nickel(II) Complexes for Catalytic Ethylene …

A Ghisolfi, C Fliedel, V Rosa, KY Monakhov… - …, 2014 - ACS Publications
Starting from the new ligands bis (diphenylphosphino)(N-4-(methylthio) phenyl) amine (4, N
(PPh2) 2 (p-C6H4) SMe) and its monosulfide derivative (Ph2P) N {P (S) Ph2}(p-C6H4) SMe …

Molybdenum (0), ruthenium (II), palladium (II), platinum (II), copper (I) and gold (I) complexes of a new methoxy functionalised bis (phosphino) amine: synthesis and …

KG Gaw, MB Smith, AMZ Slawin - New Journal of Chemistry, 2000 - pubs.rsc.org
The synthesis, and characterisation, of a new functionalised bis (phosphino) amine Ph2PN
(o-C6H4OMe) PPh21 from o-H2NC6H4OMe and 2 equiv. of Ph2PCl in diethyl ether at 0° C …

Copper (I) complexes of bis (2-(diphenylphosphino) phenyl) ether: synthesis, reactivity, and theoretical calculations

R Venkateswaran, MS Balakrishna, SM Mobin… - Inorganic …, 2007 - ACS Publications
The tricoordinated cationic CuI complex [Cu (κ2-P, P '-DPEphos)(κ1-P-DPEphos)][BF4](1)(
DPEphos= bis (2-(diphenylphosphino) phenyl) ether) containing a dangling phosphorus …

Heterofunctional Ligands Derived from Monooxidized Bis (phosphino) amines. Synthesis and Transition Metal (Rh (I), Pd (II), Pt (II)) Complexes of the Triphosphorus …

MS Balakrishna, BD Santarsiero, RG Cavell - Inorganic Chemistry, 1994 - ACS Publications
(PhO) 2 (0) PN= PPh2N (C2H5) Ph2PPtCl2. 2CH2Cl2 [at 23 C, triclinic,(No. 2), a= 11.752 (3)
A, b= 20.996 (4) A, c= 9.716 (2) A, a= 98.75 (2), ß= 105.04 (2), y= 99.04 (2), V= 2236 (1) A3 …