Photoredox-catalyzed C–H functionalization reactions
N Holmberg-Douglas, DA Nicewicz - Chemical reviews, 2021 - ACS Publications
The fields of C–H functionalization and photoredox catalysis have garnered enormous
interest and utility in the past several decades. Many different scientific disciplines have …
interest and utility in the past several decades. Many different scientific disciplines have …
Amine functionalization via oxidative photoredox catalysis: methodology development and complex molecule synthesis
JW Beatty, CRJ Stephenson - Accounts of Chemical Research, 2015 - ACS Publications
Conspectus While the use of visible light to drive chemical reactivity is of high importance to
the development of environmentally benign chemical transformations, the concomitant use …
the development of environmentally benign chemical transformations, the concomitant use …
Photoredox catalysis in organic chemistry
In recent years, photoredox catalysis has come to the forefront in organic chemistry as a
powerful strategy for the activation of small molecules. In a general sense, these approaches …
powerful strategy for the activation of small molecules. In a general sense, these approaches …
Visible-light radical reaction designed by Ru-and Ir-based photoredox catalysis
Photoredox catalysis by well-known ruthenium (II) polypyridine complexes and the relevant
Ir cyclometalated derivatives has become a powerful tool for redox reactions in synthetic …
Ir cyclometalated derivatives has become a powerful tool for redox reactions in synthetic …
[HTML][HTML] The chemistry of amine radical cations produced by visible light photoredox catalysis
Amine radical cations are highly useful reactive intermediates in amine synthesis. They have
displayed several modes of reactivity leading to some highly sought-after synthetic …
displayed several modes of reactivity leading to some highly sought-after synthetic …
Recent synthetic additions to the visible light photoredox catalysis toolbox
The boom in visible light photoredox catalysis (VLPC) research has demonstrated that this
novel synthetic approach is here to stay. VLPC enables reactive radical intermediates to be …
novel synthetic approach is here to stay. VLPC enables reactive radical intermediates to be …
Redox-neutral α-oxygenation of amines: reaction development and elucidation of the mechanism
MT Richers, M Breugst, AY Platonova… - Journal of the …, 2014 - ACS Publications
Cyclic secondary amines and 2-hydroxybenzaldehydes or related ketones react to furnish
benzo [e][1, 3] oxazine structures in generally good yields. This overall redox-neutral amine …
benzo [e][1, 3] oxazine structures in generally good yields. This overall redox-neutral amine …
Copper‐Catalyzed Regioselective Intramolecular Oxidative α‐Functionalization of Tertiary Amines: An Efficient Synthesis of Dihydro‐1, 3‐Oxazines
ML Deb, SS Dey, I Bento, MT Barros… - Angewandte …, 2013 - Wiley Online Library
Oxidative coupling reactions, especially through cross-dehydrogenative coupling (CDC) of
CÀH bonds, which avoids the prefunctionalization of substrates, have recently been in focus …
CÀH bonds, which avoids the prefunctionalization of substrates, have recently been in focus …
Reaching Green: Heterocycle Synthesis by Transition Metal‐Catalyzed C− H Functionalization in Sustainable Medium
R Santhoshkumar, CH Cheng - Chemistry–A European …, 2019 - Wiley Online Library
Catalytic C− H functionalization has emerged as an efficient alternative to traditional
coupling reactions. However, some of these reactions depend on environmentally harmful …
coupling reactions. However, some of these reactions depend on environmentally harmful …
Green synthesis of 1, 3-oxazines by visible light-promoted catalyst-free C–H activation/cyclization of tertiary amines
BS Saikia, ML Deb, PK Baruah - Environmental Chemistry Letters, 2022 - Springer
To achieve the goal of green chemistry and sustainable development, catalyst-free reactions
and use of naturally abundant resources are gaining importance. In last two decades, C–H …
and use of naturally abundant resources are gaining importance. In last two decades, C–H …