Synthetic strategies, diverse structures and tuneable properties of polyoxo-titanium clusters

WH Fang, L Zhang, J Zhang - Chemical Society Reviews, 2018 - pubs.rsc.org
As one of the most prosperous classes of cluster-based materials reported to date, polyoxo-
titanium clusters (PTCs) have been closely related to many photo-activities that broadly …

Titanium‐Oxo Clusters with Bi‐and Tridentate Organic Ligands: Gradual Evolution of the Structures from Small to Big

U Schubert - Chemistry–A European Journal, 2021 - Wiley Online Library
Homometallic titanium oxo clusters are one of the most important groups of metal oxo
clusters, with more than 300 examples characterized by X‐ray structure analyses. Most of …

Polyoxometalates: tailoring metal oxides in molecular dimension toward energy applications

L Zhang, Z Chen - International Journal of Energy Research, 2020 - Wiley Online Library
Polyoxometalates could be viewed as the molecular counterpart of the metal oxides, which
are essential ingredients for various energy conversion and storage applications. In this …

In Situ Self‐Assembled Polyoxotitanate Cages on Flexible Cellulosic Substrates: Multifunctional Coating for Hydrophobic, Antibacterial, and UV‐Blocking Applications

N Li, D Pranantyo, ET Kang… - Advanced Functional …, 2018 - Wiley Online Library
Surface coating is a powerful approach to fabricate multifunctional materials that are
essential for numerous applications. However, to achieve such multifunctional coating with a …

Acid‐Controlled Synthesis of Carboxylate‐Stabilized Ti44‐Oxo Clusters: Scaling up Preparation, Exchangeable Protecting Ligands, and Photophysical Properties

MY Gao, L Zhang, J Zhang - Chemistry–A European Journal, 2019 - Wiley Online Library
A range of polyoxotitanium clusters (PTCs) was constructed by tuning the type of acid
(inorganic and organic) in alcoholic solvents, from Ti4, Ti6, Ti9, Ti11, to Ti16. After removing …

A series of silver doped butterfly-like Ti 8 Ag 2 clusters with two Ag ions panelled on a Ti 8 surface

YZ Yu, Y Guo, YR Zhang, MM Liu, YR Feng… - Dalton …, 2019 - pubs.rsc.org
Silver doped TiO2 (Ag–TiO2) materials show high activity and good stability in
photocatalysis, but the mechanism could not be illustrated clearly due to their imprecise and …

A large titanium oxo cluster featuring a well-defined structural unit of rutile

ZF Hong, SH Xu, ZH Yan, DF Lu, XJ Kong… - Crystal Growth & …, 2018 - ACS Publications
Titanium oxo clusters (TOCs) are the well-defined molecular modes for TiO2 materials and
provide the opportunity to clarify the relationships between the structures and properties of …

Synthesis, Structures, and Photocurrent Responses of Polyoxo-Titanium Clusters with Oxime Ligands: From Ti4 to Ti18

S Chen, WH Fang, L Zhang, J Zhang - Inorganic Chemistry, 2018 - ACS Publications
Six crystalline polyoxo-titanium clusters (PTCs) derived from oximes, namely, Ti4 (μ4-
O)(OMe) 6 (L1) 4 (PTC-125; H2L1= salicylaldoxime), H [Ti5 (μ2-O)(μ3-O) 2 (OMe) 3 (L1) …

Recent advances in first‐row transition metal clusters for photocatalytic water splitting

R Chen, ZH Yan, XJ Kong - ChemPhotoChem, 2020 - Wiley Online Library
Water splitting based on first‐row transition metal (3d) photocatalysts is a cost‐effective
technology for the conversion of abundant solar energy into useful energy on a large scale …

A 4-dimethylaminobenzoate-functionalized Ti 6-oxo cluster with a narrow band gap and enhanced photoelectrochemical activity: a combined experimental and …

HT Lv, Y Cui, YM Zhang, HM Li, GD Zou… - Dalton …, 2017 - pubs.rsc.org
Organic donor–π-bridge-acceptor (D–π-A) dyes with arylamines as an electron donor have
been widely used as photosensitizers for dye-sensitized solar cells (DSSCs). However …