Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials

Y Wang, S Pan - Coordination Chemistry Reviews, 2016 - Elsevier
Metal borate halides refer to the metal borates containing additional halogen anions (ie, F,
Cl, Br or I). In recent years, motivated by the well-known high performance nonlinear optical …

Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation

G Zou, C Lin, H Jo, G Nam, TS You… - Angewandte Chemie, 2016 - Wiley Online Library
A meticulously designed, polar, non‐centrosymmetric lead borate chloride, Pb2BO3Cl, was
synthesized using KBe2BO3F2 (KBBF) as a model. Single‐crystal X‐ray diffraction revealed …

A New Deep-Ultraviolet Transparent Orthophosphate LiCs2PO4 with Large Second Harmonic Generation Response

L Li, Y Wang, BH Lei, S Han, Z Yang… - Journal of the …, 2016 - ACS Publications
LiCs2PO4, a new deep-ultraviolet (UV) transparent material, was synthesized by the flux
method. The material contains unusual edge-sharing LiO4-PO4 tetrahedra. It exhibits a very …

Pb2Ba3(BO3)3Cl: A Material with Large SHG Enhancement Activated by Pb-Chelated BO3 Groups

X Dong, Q Jing, Y Shi, Z Yang, S Pan… - Journal of the …, 2015 - ACS Publications
Pb (II) has long been associated with lone pair activity and is often substituted in alkali earth
metal borates to create new nonlinear optical (NLO) materials with enhanced second …

Synthesis of iron phosphate and their composites for lithium/sodium ion batteries

J Shao, X Li, J Wei, H Pang… - Advanced Sustainable …, 2018 - Wiley Online Library
High‐performance electric energy storage material has recently developed due to the
attention for sustainable development. As ecofriendly energy storage device, lithium ion …

Cd3(MoO4)(TeO3)2: A Polar 3D Compound Containing d10–d0 SCALP-Effect Cations

Y Feng, H Fan, Z Zhong, H Wang, D Qiu - Inorganic Chemistry, 2016 - ACS Publications
The new polar 3D cadmium molybdotellurite Cd3 (MoO4)(TeO3) 2 was obtained by means
of a high-temperature solid-state method. Cd3 (MoO4)(TeO3) 2 is a monoclinic crystal …

Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response

BP Yang, CL Hu, X Xu, C Huang, JG Mao - Inorganic Chemistry, 2013 - ACS Publications
The synthesis, crystal and electronic structures, and optical properties of the first zinc (II)
vanadium (V) iodate, namely, Zn2 (VO4)(IO3), are reported. Zn2 (VO4)(IO3) crystallizes in …

Strong Nonlinear-Optical Response in the Pyrophosphate CsLiCdP2O7 with a Short Cutoff Edge

Y Shen, S Zhao, B Zhao, C Ji, L Li, Z Sun… - Inorganic …, 2016 - ACS Publications
A high efficiency of laser-light conversion and short cutoff edge is essential to an ultraviolet
(UV) nonlinear-optical (NLO) material. Previous researches on phosphates were mainly …

ACdCO 3 F (A= K and Rb): new noncentrosymmetric materials with remarkably strong second-harmonic generation (SHG) responses enhanced via π-interaction

G Zou, G Nam, HG Kim, H Jo, TS You, KM Ok - RSC advances, 2015 - pubs.rsc.org
Two new noncentrosymmetric (NCS) materials, namely, ACdCO3F (A= K and Rb) containing
both a d10 cation (Cd2+) and a π-conjugated parallel carbonate anion (CO32−), were …

Na 7 (IO 3)(SO 4) 3: the first noncentrosymmetric alkaline-metal iodate-sulfate with isolated [IO 3] and [SO 4] units

M Ding, H Yu, Z Hu, J Wang, Y Wu - Chemical Communications, 2021 - pubs.rsc.org
Metal iodates are of current research interest because of their potential application as
nonlinear optical crystals but the exploration of new iodates is mainly concentrated on …