Transition Metal Complexes as Catalysts for the Electroconversion of CO2: An Organometallic Perspective

NW Kinzel, C Werlé, W Leitner - … Chemie International Edition, 2021 - Wiley Online Library
The electrocatalytic transformation of carbon dioxide has been a topic of interest in the field
of CO2 utilization for a long time. Recently, the area has seen increasing dynamics as an …

Highly selective electrocatalytic CO2 reduction to ethanol by metallic clusters dynamically formed from atomically dispersed copper

H Xu, D Rebollar, H He, L Chong, Y Liu, C Liu, CJ Sun… - Nature Energy, 2020 - nature.com
Direct electrochemical conversion of CO2 to ethanol offers a promising strategy to lower
CO2 emissions while storing energy from renewable electricity. However, current …

Rhenium chemistry–then and now

JR Dilworth - Coordination Chemistry Reviews, 2021 - Elsevier
The first section provides a background to the whole review. The second presents a
historical perspective of fundamental developments in rhenium chemistry from its discovery …

CO2 Activation with Manganese Tricarbonyl Complexes through an H‐Atom Responsive Benzimidazole Ligand

KK Singh, CS Gerke, SS Saund, AM Zito… - … A European Journal, 2023 - Wiley Online Library
Herein, we report the synthesis and characterization of two manganese tricarbonyl
complexes, MnI (HL)(CO) 3Br (1 a‐Br) and MnI (MeL)(CO) 3Br (1 b‐Br)(where HL= 2‐(2' …

Heterogeneous Aqueous CO2 Reduction Using a Pyrene-Modified Rhenium(I) Diimine Complex

S Sinha, A Sonea, W Shen, SS Hanson… - Inorganic …, 2019 - ACS Publications
The development of molecular catalysts and materials that can convert carbon dioxide
(CO2) into a value-added product is a great chemical challenge. Molecular catalysts set …

Strong Impact of Intramolecular Hydrogen Bonding on the Cathodic Path of [Re(3,3′-dihydroxy-2,2′-bipyridine)(CO)3Cl] and Catalytic Reduction of Carbon Dioxide

JO Taylor, G Neri, L Banerji, AJ Cowan… - Inorganic …, 2020 - ACS Publications
Herein, we present the cathodic paths of the Group-7 metal complex [Re (3, 3′-
DHBPY)(CO) 3Cl](3, 3′-DHBPY= 3, 3′-dihydroxy-2, 2′-bipyridine) producing a …

In-Depth Study of the Electronic Properties of NIR-Emissive κ3N Terpyridine Rhenium(I) Dicarbonyl Complexes

T Auvray, B Del Secco, A Dubreuil… - Inorganic …, 2020 - ACS Publications
The structure–properties relationship in a series of carbonyl rhenium (I) complexes based on
substituted terpyridine ligands of general formula [Re (κ x N-Rtpy)(CO) y L] n+ is explored by …

Aqueous CO2 Reduction by a Re(bipyridine)-polypyrrole Film Deposited on Colloid-Imprinted Carbon

J Willkomm, S Bouzidi, E Bertin, VI Birss… - ACS Catalysis, 2021 - ACS Publications
Herein, we report a [Re (bipyridine)]-carbon hybrid material for efficient and selective CO2 to
CO conversion in water. The Re catalyst was incorporated into a nanoporous colloid …

Übergangsmetallkomplexe als Katalysatoren für die elektrische Umwandlung von CO2–eine metallorganische Perspektive

NW Kinzel, C Werlé, W Leitner - Angewandte Chemie, 2021 - Wiley Online Library
Abstract Die elektrokatalytische Umwandlung von Kohlendioxid ist in der CO2‐Nutzung seit
langem von Interesse. Während sich viele Studien auf den direkten Elektronentransfer vom …

Unexpected Redox Chemistry of P∩N- and As∩N-Rhenium(I) Tricarbonyl Complexes in the Presence of CO2 Acting as an Acid

M Ertl, U Monkowius, KT Oppelt - Inorganic Chemistry, 2023 - ACS Publications
This study reports on Re tricarbonyl complexes bearing 8-(diphenylphosphanyl) quinoline,
P∩ N, and 8-(diphenylarsanyl) quinoline, As∩ N, as bidendate ligands. We studied the …