Engineering the pore size of pillared-layer coordination polymers enables highly efficient adsorption separation of acetylene from ethylene

F Zheng, L Guo, B Gao, L Li, Z Zhang… - … applied materials & …, 2019 - ACS Publications
The pore size of adsorbents plays a vital role in determining the overall separation
performance of gas separation and purification by adsorption. In this work, the pore …

Lattice expansion and ligand twist during CO 2 adsorption in flexible Cu bipyridine metal–organic frameworks

SD Marks, K Riascos-Rodriguez… - Journal of Materials …, 2020 - pubs.rsc.org
Flexible metal–organic frameworks (MOFs) can show exceptional selectivity and capacity for
adsorption of CO2. The incorporation of CO2 into flexible MOFs that have Cu2+ coordination …

Amino-functional CPL-1 with abundant CO2-philic groups to enhance MMM-based CO2 separation

H Wang, Y Ding, M Ning, M Yu, W Zheng… - Separation and …, 2023 - Elsevier
Metal organic frameworks (MOFs) with appropriate pore size and sufficient CO 2-philic
groups are required to improve the mixed matrix membranes (MMMs)-based CO 2 capture …

Hysteretic adsorption of CO 2 onto a Cu 2 (pzdc) 2 (bpy) porous coordination polymer and concomitant framework distortion

K Riascos-Rodríguez, AJ Schroeder, MR Arend… - Dalton …, 2014 - pubs.rsc.org
The present study focuses on the long-range structural changes that occur in the porous
coordination polymer Cu2 (pzdc) 2 (bpy)(pzdc= pyrazine-2, 3-dicarboxylate, bpy= 4, 4 …

Bimetallic Be/Cu Pillared-Layered Porous Coordination Polymer for Selective CO2 Removal via Adsorption

AM Tous-Granados, JC Muñoz-Senmache… - Crystal Growth & …, 2023 - ACS Publications
The rational exploration of new chemical configurations within the structural confinements of
porous coordination polymers (PCPs) continues to play a major role in developing novel …

Lithium Functionalization Promoted by Amide-Containing Ligands of a Cu(pzdc)(pia) Porous Coordination Polymer for CO2 Adsorption Enhancement

K Riascos-Rodríguez, S Marks, PG Evans… - Crystal Growth & …, 2020 - ACS Publications
A pillared layer network containing amide functional groups (Cu (pzdc)(pia); pzdc= pyrazine-
2, 3-dicarboxylate; pia= N-(4-pyridyl) isonicotinamide) was used to test a postsynthesis …

Structure of a Porous Cu2(pzdc)2(bpp) (pzdc: Pyrazine-2,3-dicarboxylate, bpp: 1,3-Bis(4-pyridyl)propane) Coordination Polymer and Flexibility upon Concomitant Hysteretic CO …

AJ Hernández-Maldonado… - Crystal Growth & …, 2015 - ACS Publications
A porous coordination polymer was prepared using pyrazine-2, 3-dicarboxylate (pzdc) and a
dipyridyl ligand that contains− CH2CH2CH2–as a spacer, namely, 1, 3-bis (4-pyridyl) …

Cu2 (pzdc) 2L [L= dipyridyl-based ligands] porous coordination polymers: Hysteretic adsorption and diffusion kinetics of CO2 and CH4

H Chen, K Riascos-Rodríguez… - Chemical Engineering …, 2016 - Elsevier
CPL-n porous coordination polymers (PCPs) in general exhibit concomitant structural
expansion during adsorption without a sudden gate-opening feature, but implications on the …

Synthesis and Characterization of a Cu2(pzdc)2(bix) [pzdc: 2,3-pyrazinedicarboxylate; bix: 1,3-bis(imidazol-1-yl)benzene] Porous Coordination Pillared-Layer …

RR Arrieta-Pérez, JN Primera-Pedrozo… - Crystal Growth & …, 2018 - ACS Publications
A porous coordination polymer (PCP) was prepared using pyrazine-2, 3-dicarboxylate
(pzdc) and the pillar ligand 1, 3-bis (imidazol-1-yl) benzene)(bix) in an attempt to improve on …

DFT analysis of coordination polymer ligands: unraveling the electrostatic properties and their effect on CO2 interaction

PJ Meza-Morales, A Santana-Vargas, MC Curet-Arana - Adsorption, 2015 - Springer
Coordination polymer with pillared layer structures, also known as coordination polymer
ligands (CPLs) are a novel class of nanoporous adsorbent materials that exhibit higher …