Tandem transformations and multicomponent reactions utilizing alcohols following dehydrogenation strategy

B Paul, M Maji, K Chakrabarti, S Kundu - Organic & Biomolecular …, 2020 - pubs.rsc.org
The construction of new C–C, C–N and C–O bonds by replacing hazardous and waste
generating chemicals with alcohols as the greener and sustainable reagents is one of the …

Transition-Metal Catalyzed Synthesis of Pyrimidines: Recent Advances, Mechanism, Scope and Future Perspectives

VK Maikhuri, D Mathur, A Chaudhary, R Kumar… - Topics in Current …, 2024 - Springer
Pyrimidine is a pharmacologically important moiety that exhibits diverse biological activities.
This review reflects the growing significance of transition metal-catalyzed reactions for the …

Ligand-controlled copper (I)-catalyzed cross-coupling of secondary and primary alcohols to α-alkylated ketones, pyridines, and quinolines

DW Tan, HX Li, DL Zhu, HY Li, DJ Young, JL Yao… - Organic …, 2018 - ACS Publications
One hexanuclear Cu (I) cluster of 4, 6-dimethylpyrimidine-2-thiolate efficiently catalyzes the
dehydrogenative cross-coupling of secondary and primary alcohols to α-alkylated ketones …

Hydrogen‐Transfer‐Mediated α‐Functionalization of 1, 8‐Naphthyridines by a Strategy Overcoming the Over‐Hydrogenation Barrier

XW Chen, H Zhao, CL Chen, HF Jiang… - Angewandte …, 2017 - Wiley Online Library
A general catalytic hydrogen transfer‐mediated α‐functionalization of 1, 8‐naphthyridines is
reported for the first time that benefits from a hydrogen transfer‐mediated activation mode for …

Direct reductive quinolyl β-C–H alkylation by multispherical cavity carbon-supported cobalt oxide nanocatalysts

F Xie, R Xie, JX Zhang, HF Jiang, L Du, M Zhang - ACS Catalysis, 2017 - ACS Publications
Until now, the selective (hetero) aryl C–H alkylation without the assistance of directing
groups or preinstallation of functionalities still remains a highly challenging goal. Herein, by …

MOF-derived nanocobalt for oxidative functionalization of cyclic amines to quinazolinones with 2-aminoarylmethanols

F Xie, QH Chen, R Xie, HF Jiang, M Zhang - ACS Catalysis, 2018 - ACS Publications
By employing a MOF-templated method, we have developed a highly dipersed and ultralow
loading cobalt nanocatalyst, which has been applied in the oxidative functionalization of …

Porous cross-linked polymer copper and iridium catalyzed the synthesis of quinoxalines and functionalized ketones under solvent-free conditions

J Li, M Yu, ZC Duan, H Zhu, W Yao… - Materials Chemistry …, 2021 - pubs.rsc.org
The development of highly active and efficient ligands is recognized to be crucial for the
catalytic applications of coordination polymers under specific conditions, such as solvent …

Acceptorless dehydrogenative coupling with Ru-based catalysts for the synthesis of N-heteroaromatic compounds

J Zhang, B Guo, DJ Young, HX Li - Dalton Transactions, 2020 - pubs.rsc.org
Ru-Catalyzed acceptorless dehydrogenative coupling (ADC) and auto-transfer-
hydrogenative (ATH) reactions are effective, versatile transformations for the constructions of …

Recent Advances in the Use of 2‐Aminobenzyl Alcohols in the Synthesis of Quinolines, Quinazolines and Other N‐Heterocycles

F Doraghi, F Gilaninezhad, S Karimian… - Advanced Synthesis …, 2024 - Wiley Online Library
N‐Heterocyclic compounds, in particular, quinolines and quinazolines are frequently used in
medicinal chemistry. Therefore, the direct and clean synthesis of these valuable scaffolds …

Aerobic copper-catalyzed synthesis of benzimidazoles from diaryl-and alkylamines via tandem triple C–H aminations

T Liang, Z Tan, H Zhao, X Chen, H Jiang… - ACS Catalysis, 2018 - ACS Publications
Through radical-induced tandem triple C–H aminations with free amines as the aminating
agents, we herein present a precedent on aerobic copper-catalyzed synthesis of 5 …