Insertion of CO2 and COS into Bi–C Bonds: Reactivity of a Bismuth NCN Pincer Complex of an Oxyaryl Dianionic Ligand,[2, 6-(Me2NCH2) 2C6H3] Bi (C6H2 t Bu2O)

DR Kindra, IJ Casely, ME Fieser, JW Ziller… - Journal of the …, 2013 - ACS Publications
The reactivity of the unusual oxyaryl dianionic ligand,(C6H2 t Bu2-3, 5-O-4) 2–, in the Bi3+
NCN pincer complex Ar′ Bi (C6H2 t Bu2-3, 5-O-4), 1,[Ar′= 2, 6-(Me2NCH2) 2C6H3] has …

Thiocyanate-Ligated Heterobimetallic {PtM} Lantern Complexes Including a Ferromagnetically Coupled 1D Coordination Polymer

JL Guillet, I Bhowmick, MP Shores, CJA Daley… - Inorganic …, 2016 - ACS Publications
A series of heterobimetallic lantern complexes with the central unit {PtM (SAc) 4 (NCS)} have
been prepared and thoroughly characterized. The {Na (15C5)}[PtM (SAc) 4 (NCS)] series, 1 …

Shape and Phase‐Controlled One‐Pot Synthesis of Air Stable Cationic AgCdS Nanocrystals, Optoelectronic and Electrochemical Hydrogen Evolution Studies

J Chaturvedi, ATM Munthasir, AK Nayak… - Small …, 2024 - Wiley Online Library
CdS‐based materials are extensively studied for photocatalytic water splitting. By
incorporating Ag+ into CdS nanomaterials, the catalyst's charge carrier dynamic can be …

Evolution of metal-thiocarboxylate chemistry in 21st century

S Singh - Journal of Molecular Structure, 2021 - Elsevier
Metal-thiocarboxylate complexes have interesting features in coordination chemistry as well
as in material applications along with some role in the biological system. Which are glint by …

O-versus S-Metal Coordination of the Thiocarboxylate Group: An NMR Study of the Two Tautomeric Forms of the Ga (III)-Photoxenobactin E Complex

L Buedenbender, L Ageitos, MA Lages… - Inorganic …, 2024 - ACS Publications
Photoxenobactin E (1) is a natural product with an unusual thiocarboxylic acid terminus
recently isolated from an entomopathogenic bacterium. The biosynthetic gene cluster …

A semiconducting microporous framework of Cd 6 Ag 4 (SPh) 16 clusters interlinked using rigid and conjugated bipyridines

C Xu, N Hedin, HT Shi, QF Zhang - Chemical Communications, 2014 - pubs.rsc.org
Ternary supertetrahedral chalcogenolate clusters were interlinked with bipyridines into a
microporous semiconducting framework with properties qualitatively different from those of …

Zinc and cadmium thioamidate complexes: rational design of single-source precursors for the AACVD of ZnS

ME Robson, AL Johnson - Dalton Transactions, 2024 - pubs.rsc.org
A series of zinc (II) thioamidate complexes [Zn {SC (iPr) NR} 2] n for R= iPr (n= 2)(2), tBu
(3)(n= 1), Ph (4)(n= 2) and Cy (5)(n= 2) and one cadmium (II) thioamidate complex [Cd {SC …

Studies of synthesis, structural features of Cu (I) thiophene-2-thiocarboxylates and unprecedented desulfurization of Cu (II) thiocarboxylate complexes

S Singh, J Chaturvedi, S Bhattacharya - Dalton Transactions, 2012 - pubs.rsc.org
Thiophene-2-thiocarboxylate complexes of Cu (I),[(Ph3P) 2Cu (SCOth)](1) and H [(Ph3P)
2Cu (SCOth) 2](2)(where th= thiophene) were synthesized and characterized structurally by …

Synthesis and Structures of Cadmium Carboxylate and Thiocarboxylate Compounds with a Sulfur-Rich Coordination Environment: Carboxylate Exchange Kinetics Involving Tris(2-mercapto-1-t …

A Kreider-Mueller, PJ Quinlivan, JS Owen… - Inorganic …, 2015 - ACS Publications
A series of cadmium carboxylate compounds in a sulfur-rich environment provided by the tris
(2-tert-butylmercaptoimidazolyl) hydroborato ligand, namely,[TmBut] CdO2CR, has been …

Synthesis of a series of Cd (ii) furan-2-thiocarobxylates: unprecedented coordination geometry of a Cd (ii) complex exhibiting catalytic efficiency for the synthesis of 3 …

K Kumar, A Shrivastav, AR Choudhury… - New Journal of …, 2024 - pubs.rsc.org
A series of Cd (II) complexes,[(PPh3) 2Cd (SCOf) 2](1),[PPh4] 2 [Cd (SCOf) 2 (μ-Br)] 2
(2),[(PPh3) 2Ag (μ2-SCOf) 2Cd (SCOf)](3), Na2 [(PPh3) Cd (MeOH)(SCOf) 3] 2 (4a) and Na2 …