Siloxane coordination revisited: Si− O bond character, reactivity and magnificent molecular shapes
F Dankert, C von Hänisch - European Journal of Inorganic …, 2021 - Wiley Online Library
Siloxanes have evolved into a multi‐million dollar business due to their manifold of
commercial and industrial applications. As siloxanes have high hydrophobicity, low basicity …
commercial and industrial applications. As siloxanes have high hydrophobicity, low basicity …
Recent advances in organo-lanthanides and actinides mediated hydroaminations
Hydroamination, an atom-economic one-step reaction that refers to the addition of an NH
unit into CC/CX multiple bonds, provides an ideally efficient methodology to construct C–N …
unit into CC/CX multiple bonds, provides an ideally efficient methodology to construct C–N …
Reduction vs. addition: the reaction of an aluminyl anion with 1, 3, 5, 7‐cyclooctatetraene
The potassium aluminyl complex K [Al (NONAr)](NON= NONAr=[O (SiMe2NAr) 2] 2−, Ar= 2,
6‐iPr2C6H3) reacts with 1, 3, 5, 7‐cyclooctatetraene (COT) to give K [Al (NONAr)(COT)]. The …
6‐iPr2C6H3) reacts with 1, 3, 5, 7‐cyclooctatetraene (COT) to give K [Al (NONAr)(COT)]. The …
Self-assembly of Keggin-type U (VI)-containing tungstophosphates with a sandwich structure: an efficient catalyst for the synthesis of sulfonyl pyrazoles
GP Yang, XL Zhang, YF Liu, DD Zhang, K Li… - Inorganic Chemistry …, 2021 - pubs.rsc.org
The reaction of UO2 (OAc) 2 and Na9 [A-PW9O34] in solution with different pH values leads
to the formation of two Keggin-type sandwich polyoxometalates, namely Na11H (H2O) 31 …
to the formation of two Keggin-type sandwich polyoxometalates, namely Na11H (H2O) 31 …
Zinc Catalyzed Hydroelementation (HE; E= B, C, N, and O) of Carbodiimides: Intermediates Isolation and Mechanistic Insights
The conjugated bis-guanidinate (CBG) supported zinc hydride,[{LZnH} 2; L={(ArHN)(ArN)-
C═ N–C═(NAr)(NHAr); Ar= 2, 6-Et2-C6H3}](1)(pre)-catalyzed addition of E–H (E= B, C, N …
C═ N–C═(NAr)(NHAr); Ar= 2, 6-Et2-C6H3}](1)(pre)-catalyzed addition of E–H (E= B, C, N …
Recent developments in highly basic N-heterocyclic iminato ligands in actinide chemistry
In the last decade, major conceptual advances in the chemistry of actinide molecules and
materials have been made to demonstrate their distinct reactivity profiles as compared to …
materials have been made to demonstrate their distinct reactivity profiles as compared to …
The role of 5f-orbital participation in unexpected inversion of the σ-bond metathesis reactivity trend of triamidoamine thorium (IV) and uranium (IV) alkyls
BM Gardner, PA Cleaves, CE Kefalidis, J Fang… - Chemical …, 2014 - pubs.rsc.org
We report on the role of 5f-orbital participation in the unexpected inversion of the σ-bond
metathesis reactivity trend of triamidoamine thorium (IV) and uranium (IV) alkyls. Reaction of …
metathesis reactivity trend of triamidoamine thorium (IV) and uranium (IV) alkyls. Reaction of …
Actinide‐Mediated Catalytic Addition of E H Bonds (E= N, P, S) to Carbodiimides, Isocyanates, and Isothiocyanates
Unprecedented catalytic reactivity of actinide coordination complexes toward
heterocumulenes, such as carbodiimides, isocyanates, and isothiocyanates is reported. The …
heterocumulenes, such as carbodiimides, isocyanates, and isothiocyanates is reported. The …
Mono (imidazolin-2-iminato) actinide complexes: synthesis and application in the catalytic dimerization of aldehydes
The synthesis of the mono (imidazolin-2-iminato) actinide (IV) complexes [(ImRN) An (N
{SiMe3) 2} 3](3–8) was accomplished by the protonolysis reaction between the respective …
{SiMe3) 2} 3](3–8) was accomplished by the protonolysis reaction between the respective …
Effect of Na(I)-H2O clusters on self-assembly of sandwich-type U(VI)-containing silicotungstates and the efficient catalytic activity for the synthesis of substituted phenylsulfonyl-1 …
K Li, XL Lin, K Zeng, XF Gao, W Cen, YF Liu, GP Yang - Tungsten, 2022 - Springer
In this study, a sandwich-type uranium (VI)-containing silicotungstate KNa 11 H 2 (H 2 O) 30
[Na (UO 2)(SiW 9 O 34)] 2· 8H 2 O (1) with new three-dimensional (3D) structure was …
[Na (UO 2)(SiW 9 O 34)] 2· 8H 2 O (1) with new three-dimensional (3D) structure was …