Polyoxometalates: building blocks for functional nanoscale systems
DL Long, R Tsunashima… - Angewandte Chemie …, 2010 - Wiley Online Library
Polyoxometalates (POMs) are a subset of metal oxides that represent a diverse range of
molecular clusters with an almost unmatched range of physical properties and the ability to …
molecular clusters with an almost unmatched range of physical properties and the ability to …
Structure, properties and reactivity of polyoxometalates: a theoretical perspective
In the thematic review dedicated to polyoxometalate (POM) chemistry published in Chemical
Reviews in 1998, no contribution was devoted to theory. This is not surprising because …
Reviews in 1998, no contribution was devoted to theory. This is not surprising because …
[HTML][HTML] Tuning the reactivity of carbon surfaces with oxygen-containing functional groups
Oxygen-containing carbons are promising supports and metal-free catalysts for many
reactions. However, distinguishing the role of various oxygen functional groups and …
reactions. However, distinguishing the role of various oxygen functional groups and …
Controlling the isolation and pairing of aluminum in chabazite zeolites using mixtures of organic and inorganic structure-directing agents
JR Di Iorio, R Gounder - Chemistry of Materials, 2016 - ACS Publications
Synthetic methods are reported to prepare chabazite (CHA) zeolites (SSZ-13) at fixed
elemental composition but with different arrangements of their framework Al atoms (Al–O …
elemental composition but with different arrangements of their framework Al atoms (Al–O …
Selective hydrogenolysis of polyols and cyclic ethers over bifunctional surface sites on rhodium–rhenium catalysts
A ReO x-promoted Rh/C catalyst is shown to be selective in the hydrogenolysis of secondary
C–O bonds for a broad range of cyclic ethers and polyols, these being important classes of …
C–O bonds for a broad range of cyclic ethers and polyols, these being important classes of …
Structure and Dynamics of Zr6O8 Metal–Organic Framework Node Surfaces Probed with Ethanol Dehydration as a Catalytic Test Reaction
Some metal–organic frameworks (MOFs) incorporate nodes that are metal oxide clusters
such as Zr6O8. Vacancies on the node surfaces, accidental or by design, act as catalytic …
such as Zr6O8. Vacancies on the node surfaces, accidental or by design, act as catalytic …
Strategies for incorporating catalytically active polyoxometalates in metal–organic frameworks for organic transformations
Polyoxometalates (POMs) can benefit from immobilization on solid supports to overcome
their difficulty in processability and stability. Among the reported solid supports, metal …
their difficulty in processability and stability. Among the reported solid supports, metal …
Recent advances in polyoxometalates acid-catalyzed organic reactions
YF Liu, CW Hu, GP Yang - Chinese Chemical Letters, 2023 - Elsevier
Polyoxometalates (POMs) have conducive properties such as controlled Brønsted and
Lewis acidity, high thermal stability, nontoxic nature, tunable solubility, and less …
Lewis acidity, high thermal stability, nontoxic nature, tunable solubility, and less …
The catalytic diversity of zeolites: confinement and solvation effects within voids of molecular dimensions
The ability of molecular sieves to control the access and egress of certain reactants and
products and to preferentially contain certain transition states while excluding others based …
products and to preferentially contain certain transition states while excluding others based …
[HTML][HTML] Structure and solvation of confined water and water–ethanol clusters within microporous Brønsted acids and their effects on ethanol dehydration catalysis
Aqueous-phase reactions within microporous Brønsted acids occur at active centers
comprised of water-reactant-clustered hydronium ions, solvated within extended hydrogen …
comprised of water-reactant-clustered hydronium ions, solvated within extended hydrogen …