Emerging trends in polymerization-induced self-assembly

NJW Penfold, J Yeow, C Boyer, SP Armes - ACS Macro Letters, 2019 - ACS Publications
In this Perspective, we summarize recent progress in polymerization-induced self-assembly
(PISA) for the rational synthesis of block copolymer nanoparticles with various …

RAFT‐mediated polymerization‐induced self‐assembly

F d'Agosto, J Rieger, M Lansalot - … Chemie International Edition, 2020 - Wiley Online Library
After a brief history that positions polymerization‐induced self‐assembly (PISA) in the field of
polymer chemistry, this Review will cover the fundamentals of the PISA mechanism …

Polymerization techniques in polymerization-induced self-assembly (PISA)

C Liu, CY Hong, CY Pan - Polymer Chemistry, 2020 - pubs.rsc.org
The development of controlled/“living” polymerization greatly stimulated the prosperity of the
fabrication and application of block copolymer nano-objects. Controlled/“living” …

Getting into shape: reflections on a new generation of cylindrical nanostructures' self-assembly using polymer building blocks

JC Foster, S Varlas, B Couturaud, Z Coe… - Journal of the …, 2019 - ACS Publications
Cylinders are fascinating structures with uniquely high surface area, internal volume, and
rigidity. On the nanoscale, a broad range of applications have demonstrated advantageous …

Principles and characteristics of polymerization-induced self-assembly with various polymerization techniques

EJ Cornel, J Jiang, S Chen, J Du - CCS Chemistry, 2021 - chinesechemsoc.org
A chemical reaction that drives a physical polymer self-assembly process, namely,
polymerization-induced self-assembly (PISA), combines block copolymer synthesis and …

Complex polymer architectures using ring-opening metathesis polymerization: synthesis, applications, and practical considerations

SE Blosch, SJ Scannelli, M Alaboalirat… - Macromolecules, 2022 - ACS Publications
Nature shows us that complex molecular architectures lead to unique material properties,
and these observations have driven polymer scientists to synthesize complex architectures …

Self-assembled nanostructures from amphiphilic block copolymers prepared via ring-opening metathesis polymerization (ROMP)

S Varlas, SB Lawrenson, LA Arkinstall… - Progress in Polymer …, 2020 - Elsevier
The development of controlled/living polymerization methodologies has underpinned a
rapid expanse in our understanding of amphiphilic block copolymer self-assembly. In …

Tuning the membrane permeability of polymersome nanoreactors developed by aqueous emulsion polymerization-induced self-assembly

S Varlas, JC Foster, PG Georgiou, R Keogh… - Nanoscale, 2019 - pubs.rsc.org
Polymeric vesicles (or polymersomes) are hollow bilayer structures consisting of an inner
aqueous compartment enclosed by a hydrophobic membrane. Vesicular constructs are …

Triggered polymersome fusion

SDP Fielden, MJ Derry, AJ Miller… - Journal of the …, 2023 - ACS Publications
The contents of biological cells are retained within compartments formed of phospholipid
membranes. The movement of material within and between cells is often mediated by the …

Proapoptotic Peptide Brush Polymer Nanoparticles via Photoinitiated Polymerization‐Induced Self‐Assembly

H Sun, W Cao, N Zang, TD Clemons… - Angewandte …, 2020 - Wiley Online Library
Herein, we report the photoinitiated polymerization‐induced self‐assembly (photo‐PISA) of
spherical micelles consisting of proapoptotic peptide–polymer amphiphiles. The one‐pot …