Organoelement chemistry: Promising growth areas and challenges
GA Abakumov, AV Piskunov… - Russian Chemical …, 2018 - iopscience.iop.org
The chemistry of organoelement compounds is now one of the most rapidly developing
fields of research, regarding both fundamental science and solution of applied problems …
fields of research, regarding both fundamental science and solution of applied problems …
Перспективные точки роста и вызовы элементоорганической химии
ГА Абакумов, АВ Пискунов, ВК Черкасов… - Успехи химии, 2018 - mathnet.ru
Химия элементоорганических соединений в настоящее время—одна из самых
динамично развивающихся научных областей как в плане фундаментальных …
динамично развивающихся научных областей как в плане фундаментальных …
Electrooxidation of Hypercoordinated Derivatives of Silicon and Reactivity of Their Electrogenerated Cation Radicals: 1-Substituted Silatranes
V Romanovs, EF Belogolova, EP Doronina… - Molecules, 2023 - mdpi.com
Electrochemical oxidation of 1-R-substituted silatranes 1 (R= Me, vinyl,(CH2) 2CN, CH2Ph,
CH2 (C10H7), Ph, C6H4Me, p-Cl-C6H4, Cl)—classical representatives of pentacoordinated …
CH2 (C10H7), Ph, C6H4Me, p-Cl-C6H4, Cl)—classical representatives of pentacoordinated …
Electrochemical Oxidation and Radical Cations of Structurally Non‐rigid Hypervalent Silatranes: Theoretical and Experimental Studies
VF Sidorkin, EF Belogolova, Y Wang… - … A European Journal, 2017 - Wiley Online Library
Abstract Using 18 silatranes XSi (OCH2CH2) 3N (1) as examples, the potentials of
electrochemical oxidation E0 of the hypervalent compounds of Si were calculated for the first …
electrochemical oxidation E0 of the hypervalent compounds of Si were calculated for the first …
Novel Stannatranes of the Type N(CH2CMe2O)3SnX (X = OR, SR, OC(O)R, SP(S)Ph2, Halogen). Synthesis, Molecular Structures, and Electrochemical Properties
T Zöller, C Dietz, L Iovkova-Berends… - Inorganic …, 2012 - ACS Publications
The syntheses of the stannatrane derivatives of the type N (CH2CMe2O) 3SnX (1, X= O t-Bu;
2, X= O i-Pr; 3, X= 2, 6-Me2C6H3O; 4, X= pt-BuC6H4O; 5, X= p-NO2C6H4O; 6, X= p …
2, X= O i-Pr; 3, X= 2, 6-Me2C6H3O; 4, X= pt-BuC6H4O; 5, X= p-NO2C6H4O; 6, X= p …
Germanium‐centered Ion Radicals
MP Egorov, VV Jouikov… - Organogermanium …, 2023 - Wiley Online Library
Primary products of single‐electron transfer to/from organogermanium compounds (anion
radicals and cation radicals issued from reduction and oxidation, respectively) and their …
radicals and cation radicals issued from reduction and oxidation, respectively) and their …
Covalent grafting of silatranes to carbon interfaces
C Peureux, V Jouikov - Chemistry–A European Journal, 2014 - Wiley Online Library
Abstract Covalent Si C grafting of a silatrane cage to a carbon‐based interface provides a
truly conjugated benzyl‐type system in which the 3 c–4 e orbital of the silatrane interacts …
truly conjugated benzyl‐type system in which the 3 c–4 e orbital of the silatrane interacts …
Cation radicals of organogermatranes
S Soualmi, L Ignatovich… - Applied Organometallic …, 2010 - Wiley Online Library
Abstract Cation radicals (CRs) of 1‐substituted germatranes were generated by one‐
electron electrochemical oxidation and studied by real‐time EPR spectroscopy for the first …
electron electrochemical oxidation and studied by real‐time EPR spectroscopy for the first …
Synthesis and electrochemical study of 1, 1′-thienyl-substituted fused bis-germatranes with a core 5c-6e hyperbond
V Romanovs, J Spura, V Jouikov - Synthesis, 2018 - thieme-connect.com
Novel fused bis-germatranes containing three hypercoordinated atoms (two Ge and one N)
and substituted at the 1, 1′-positions with bromo-thienyl groups [(3-bromo-2-thienyl)-,(3, 5 …
and substituted at the 1, 1′-positions with bromo-thienyl groups [(3-bromo-2-thienyl)-,(3, 5 …
Radical cations of phenyl silatrane
V Romanovs, V Sidorkin, E Belogolova… - Dalton Transactions, 2017 - pubs.rsc.org
Electrochemical oxidation of phenylsilatrane (1) in CH3CN/0.1 M Bu4NPF6 has been
studied by voltammetry, UV-Vis and EPR-coupled spectroelectrochemistry supported by …
studied by voltammetry, UV-Vis and EPR-coupled spectroelectrochemistry supported by …