Hydrosilanes are used as versatile coreactants in the generation of silyl-metal complexes.
Since organohydrosilanes may contain one, two, or three SiH bonds as tertiary, secondary …

The discovery by Kubas et al. 1 of the coordination of an intact dihydrogen molecule to
transition metals to form a dihydrogen s-complex 1 was one of the most exciting and …

A DFT/B3LYP model study has been carried out on the cyclocarbopalladation and on an
unusual 1, 5 vinyl to aryl palladium shift which are the two first steps of a …

Copper(I) Alkyne and Alkynide Complexes | Organometallics ACS ACS Publications C&EN CAS
Find my institution Log In Organometallics ACS Publications. Most Trusted. Most Cited. Most …

The agostic bond defines an intramolecular interaction where a σ bond is geometrically
close to an electron deficient centre (often a transition metal). The computational studies on …

The cation− π interactions have been intensively studied. Nevertheless, the interactions of π
systems with heavy transition metals and their accurate conformations are not well …

Copper (I) chalcogenones with rare Cu⋯ H–C (sp3) hydrogen bonding interactions have
been reported. The copper (I) bis (benzimidazole-2-chalcogenone) complexes [Cu (L1) 4]+ …

The complexes formed by CuF with CC double and triple bonds have been studied at the
MP2 and CCSD (T) computational levels. The interaction of CuF with acetylene, ethylene …

In this review, we present a general overview on the studies carried out on Ni+‐‐and Ni2+‐
containing systems in the gas phase since 1996. We have focused our attention in the …

It is shown that the Siδ+ Hδ-⋯⊃ Al interaction, where '⊃'denotes the electron lone-pair
vacancy, may exist if Siδ+ Hδ-and⊃ Al subunits belong to the same molecule, ie they may …