Au (III) Cyclometallated Compounds with 2-Arylpyridines and Their Derivatives or Analogues: 34 Years (1989–2022) of NMR and Single Crystal X-ray Studies

L Pazderski, PA Abramov - Inorganics, 2023 - mdpi.com
A review paper on Au (III) cyclometallated compounds with 2-arylpyridines (2-
phenylpyridine, 2-benzylpyridine, 2-benzoylpyridine, 2-phenoxypyridine, 2 …

Metal halide perovskites for CO2 photoreduction: recent advances and future perspectives

Z Dong, B Li, Y Zhu, W Guo - EES Catalysis, 2024 - pubs.rsc.org
CO2 emission has inarguably become one of the greatest challenges ever faced by
mankind since industrial revolution. Techniques aiming at capture, storage and utilization of …

Blue Iridium (III) Phosphorescent OLEDs with High Brightness Over 10 000 cd m−2 and Ultralow Efficiency Roll‐Off

C Wu, M Wang, KN Tong, M Zhang, W Li… - Advanced Optical …, 2023 - Wiley Online Library
Herein, a family of six [3+ 2+ 1] coordinated 2‐(2′, 4′‐difluorophenyl) pyridine‐based
Iridium (III) complexes with intermolecular interactions have been designed to improve their …

Against the norm: non Irving–Williams transmetalation in transition metal dimers

SS Woodhouse, TN Dais, A Etcheverry-Berríos… - Inorganic …, 2022 - ACS Publications
We report the synthesis and characterization of three dinuclear 3 d 3 d′ complexes, CuCu
([C u 2 IIL (NO 3) 2]), MnMn ([M n 2 IIL (M e OH) 2 (NO 3) 2]), and CuMn ([CuIIMnII L (NO3) …

A Conformationally Restricted Gold (III) Complex Elicits Antiproliferative Activity in Cancer Cells

S Gukathasan, OA Obisesan, S Saryazdi… - Inorganic …, 2023 - ACS Publications
Diamine ligands are effective structural scaffolds for tuning the reactivity of transition-metal
complexes for catalytic, materials, and phosphorescent applications and have been …

Catalysis toward metal-based substrates: A new prospect for inorganic chemistry

F López-Gallego, L Salassa - Chem Catalysis, 2023 - cell.com
Although nature has evolved numerous enzymes that use metals as substrates, artificial
catalytic transformations of transition metals are rarely explored in chemistry. Only a handful …

(P^ N^ C) Ligands to Stabilize Gold (III): A Straightforward Access to Hydroxo, Formate, and Hydride Complexes

J Martín, J Schörgenhumer, M Biedrzycki… - Inorganic …, 2024 - ACS Publications
A novel class of (P^ N^ C) pincer ligands capable of stabilizing elusive gold (III) species is
reported here. Straightforward access to (P^ N^ C) gold (III) hydroxo, formate, and hydride …

Gold (III), Mercury (II), and Palladium (II) Complexes of a Series of Isomeric Bis (mono-and dialkoxyphenyl) pyridines: Introduction of Gold through Transmetalation and …

AJ McEllin, CA Goult, G Mohiuddin, LJ Curtis… - Inorganic …, 2024 - ACS Publications
A series of isomeric bis-2, 6-(monoalkoxyphenyl) pyridine and bis-2, 6-(dialkoxyphenyl)
pyridine ligands were synthesized and characterized. In order to prepare their chlorogold …

On the mercuration, palladation, transmetalation and direct auration of a C^ N^ C pincer ligand

AJ McEllin, CA Goult, AC Whitwood, JM Lynam… - Dalton …, 2023 - pubs.rsc.org
The C^ N^ C ligand 2, 6-bis (2, 3-dialkoxyphenyl) pyridine forms dimercury and
orthopalladated complexes, both of which may be transmetallated to gold (III) complexes; …

Functional organogold (III) complexes with bidentate cyclometalating ligands

VKM Au - Journal of Organometallic Chemistry, 2023 - Elsevier
The advancement of organometallic chemistry over the past decades has accelerated the
development of functional materials based on metal complexes. In particular, organometallic …