Synthetic Advances for Mechanistic Insights: Metal–Oxygen Intermediates with a Macrocyclic Pyridinophane System
D Jeong, K Kim, Y Lee, J Cho - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Metalloenzymes, which are proteins containing earth-abundant transition-metal
ions as cofactors in the active site, generate various metal–oxygen intermediates via …
ions as cofactors in the active site, generate various metal–oxygen intermediates via …
A cluster-nanozyme-coenzyme system mimicking natural photosynthesis for CO2 reduction under intermittent light irradiation
X Cui, H Bai, J Zhang, R Liu, H Yu, Y Wang… - Nature …, 2024 - nature.com
Natural photosynthesis utilizes solar energy to convert water and atmospheric CO2 into
carbohydrates through all-weather light/dark reactions based on molecule-based enzymes …
carbohydrates through all-weather light/dark reactions based on molecule-based enzymes …
Controlling Reactivity through Spin Manipulation: Steric Bulkiness of Peroxocobalt (III) Complexes
S Kim, Y Lee, GL Tripodi, J Roithová… - Journal of the …, 2024 - ACS Publications
The intrinsic relationship between spin states and reactivity in peroxocobalt (III) complexes
was investigated, specifically focusing on the influence of steric modulation on supporting …
was investigated, specifically focusing on the influence of steric modulation on supporting …
Mechanistic Insights into Nitrile Activation by Cobalt (III)–Hydroperoxo Intermediates: The Influence of Ligand Basicity
Y Son, D Jeong, K Kim, J Cho - JACS Au, 2023 - ACS Publications
The versatile applications of nitrile have led to the widespread use of nitrile activation in the
synthesis of pharmacologically and industrially valuable compounds. We reported the …
synthesis of pharmacologically and industrially valuable compounds. We reported the …
Rings of Power: Controlling SOD Mimic Activity by the Addition of Pyridine Rings within the Pyridinophane Scaffold
KJ Smith, TM Schwartz, DM Freire, CJ Bowers… - Inorganic …, 2024 - ACS Publications
Superoxide dismutase enzymes are a major defense against superoxide, which is a potent
reactive oxygen species. Misregulation of reactive oxygen species and subsequent …
reactive oxygen species. Misregulation of reactive oxygen species and subsequent …
Synthesis and Characterization of RPy2N2 Pyridinophane Ligands and Transition Metal Complexes as Therapeutics and Catalysts
KJ Smith - 2024 - search.proquest.com
The pyridinophane family of macrocycles has been studied for decades as ligand scaffolds
for metals towards a wide variety of applications including biological mimics, catalysts, and …
for metals towards a wide variety of applications including biological mimics, catalysts, and …