Metal-organic frameworks in Russia: From the synthesis and structure to functional properties and materials

MA Agafonov, EV Alexandrov, NA Artyukhova… - Journal of Structural …, 2022 - Springer
Current research fields of metal-organic frameworks (MOFs), which are being developed in
the last 5-10 years by Russian scientific institutions and universities, are generalized. The …

Control of electronic polarization via charge ordering and electron transfer: electronic ferroelectrics and electronic pyroelectrics

SQ Su, SQ Wu, S Kanegawa, K Yamamoto… - Chemical Science, 2023 - pubs.rsc.org
Ferroelectric, pyroelectric, and piezoelectric compounds whose electric polarization
properties can be controlled by external stimuli such as electric field, temperature, and …

Broad electronic modulation of two-dimensional metal–organic frameworks over four distinct redox states

L Wang, A Sarkar, GL Grocke… - Journal of the …, 2023 - ACS Publications
Two-dimensional (2D) inorganic materials have emerged as exciting platforms for (opto)
electronic, thermoelectric, magnetic, and energy storage applications. However, electronic …

Manipulating electron redistribution to achieve electronic pyroelectricity in molecular [FeCo] crystals

P Sadhukhan, SQ Wu, JI Long, T Nakanishi… - Nature …, 2021 - nature.com
Pyroelectricity plays a crucial role in modern sensors and energy conversion devices.
However, obtaining materials with large and nearly constant pyroelectric coefficients over a …

Enhanced Single‐Chain Magnet Behavior via Anisotropic Exchange in a Cyano‐Bridged MoIII–MnII Chain

L Shi, D Shao, XQ Wei, KR Dunbar… - Angewandte Chemie …, 2020 - Wiley Online Library
Anisotropic magnetic exchange is of great value for the design of high performance
molecular nanomagnets. In the present work, enhanced single‐chain magnet (SCM) …

Coercive fields above 6 T in two cobalt (II)–radical chain compounds

X Liu, X Feng, KR Meihaus, X Meng… - Angewandte …, 2020 - Wiley Online Library
Lanthanide permanent magnets are widely used in applications ranging from
nanotechnology to industrial engineering. However, limited access to the rare earths and …

Elucidating metal and ligand redox activities of a copper-benzoquinoid coordination polymer as the cathode for lithium-ion batteries

CH Chang, AC Li, I Popovs, W Kaveevivitchai… - Journal of materials …, 2019 - pubs.rsc.org
A novel redox-active quinone-based organic building block 1, 4-dicyano-2, 3, 5, 6-
tetrahydroxybenzene (LH4) has been synthesized and used as a bridging ligand to form a …

Thermally Induced Valence Tautomeric Transition in a Two‐Dimensional Fe‐Tetraoxolene Honeycomb Network

J Chen, Y Sekine, Y Komatsumaru… - Angewandte Chemie …, 2018 - Wiley Online Library
A novel tetraoxolene‐bridged Fe two‐dimensional honeycomb layered compound,(NPr4) 2
[Fe2 (Cl2An) 3]⋅ 2 (acetone)⋅ H2O (1), where Cl2Ann−= 2, 5‐dichloro‐3, 6‐dihydroxy‐1, 4 …

Redox-active benzoquinones as challenging “non-innocent” linkers to construct 2D frameworks and nanostructures with tunable physical properties

N Monni, MS Angotzi, M Oggianu… - Journal of Materials …, 2022 - pubs.rsc.org
Exploiting redox activity in supramolecular frameworks such as coordination polymers, metal–
organic frameworks and related nanostructures is of paramount importance both at the …

Coordination chemistry of nitronyl nitroxide radicals has memory

D Luneau - European Journal of Inorganic Chemistry, 2020 - Wiley Online Library
Nitronyl nitroxide free radicals, and particularly their coordination compounds, have played a
major role in the development of molecular‐based magnetic materials. Nevertheless, recent …