Tracking surface charge dynamics on single nanoparticles
Surface charges play a fundamental role in physics and chemistry, in particular in shaping
the catalytic properties of nanomaterials. However, tracking nanoscale surface charge …
the catalytic properties of nanomaterials. However, tracking nanoscale surface charge …
Charge regulated solid-liquid interfaces interacting on the nanoscale: Benchmarking of a generalized speciation code (SINFONIA)
T Gil-Díaz, D Jara-Heredia, F Heberling… - Advances in Colloid and …, 2021 - Elsevier
Surface chemistry of mineral phases in aqueous environments generates the electrostatic
forces involved in particle-particle interactions. However, few models directly take into …
forces involved in particle-particle interactions. However, few models directly take into …
Charge regulation effects in nanoparticle self-assembly
Nanoparticles in solution acquire charge through the dissociation or association of surface
groups. Thus, a proper description of their electrostatic interactions requires the use of …
groups. Thus, a proper description of their electrostatic interactions requires the use of …
Theory of charge regulation of colloidal particles in electrolyte solutions
We present a theory that enables us to (i) calculate the effective surface charge of colloidal
particles and (ii) efficiently obtain titration curves for different salt concentrations. The theory …
particles and (ii) efficiently obtain titration curves for different salt concentrations. The theory …
Disparate External Electric Field Effect on the Adsorption and Shear Behavior of Monovalent and Trivalent Ions in Electrolyte Solution
R Zhao, T Han, C Zhang, Q Yu - Nano Letters, 2024 - ACS Publications
Reducing friction is of great interest, and an external potential applied to the friction pair can
regulate lubricity. Electrochemical atomic force microscopy (EC-AFM) is used to study the …
regulate lubricity. Electrochemical atomic force microscopy (EC-AFM) is used to study the …
Modeling surface charge regulation of colloidal particles in aqueous solutions
GMC Ong, A Gallegos, J Wu - Langmuir, 2020 - ACS Publications
Colloidal particles are mostly charged in an aqueous solution because of the protonation or
deprotonation of ionizable groups on the surface. The surface charge density reflects a …
deprotonation of ionizable groups on the surface. The surface charge density reflects a …
Charge regulation of colloidal particles in aqueous solutions
We study the charge regulation of colloidal particles inside aqueous electrolyte solutions. To
stabilize a colloidal suspension against precipitation, colloidal particles are synthesized with …
stabilize a colloidal suspension against precipitation, colloidal particles are synthesized with …
Titration in Canonical and Grand-Canonical Ensembles
A Bakhshandeh, Y Levin - The Journal of Physical Chemistry B, 2023 - ACS Publications
We discuss problems associated with the notion of pH in heterogeneous systems. For
homogeneous systems, standardization protocols lead to a well-defined quantity, which …
homogeneous systems, standardization protocols lead to a well-defined quantity, which …
Reactive Monte Carlo simulations for charge regulation of colloidal particles
We use a reactive Monte Carlo simulation method and the primitive model of electrolyte to
study acid–base equilibrium that controls charge regulation in colloidal systems. The …
study acid–base equilibrium that controls charge regulation in colloidal systems. The …
Interfacial solvation can explain attraction between like-charged objects in aqueous solution
A Kubincová, PH Hünenberger… - The Journal of chemical …, 2020 - pubs.aip.org
Over the past few decades, the experimental literature has consistently reported
observations of attraction between like-charged colloidal particles and macromolecules in …
observations of attraction between like-charged colloidal particles and macromolecules in …