Multiblock copolymer synthesis via RAFT emulsion polymerization

GKK Clothier, TR Guimarães, SW Thompson… - Chemical Society …, 2023 - pubs.rsc.org
A multiblock copolymer is a polymer of a specific structure that consists of multiple covalently
linked segments, each comprising a different monomer type. The control of the monomer …

Bioactive synthetic polymers

K Jung, N Corrigan, EHH Wong, C Boyer - Advanced Materials, 2022 - Wiley Online Library
Synthetic polymers are omnipresent in society as textiles and packaging materials, in
construction and medicine, among many other important applications. Alternatively, natural …

50th Anniversary Perspective: RAFT PolymerizationA User Guide

S Perrier - Macromolecules, 2017 - ACS Publications
This Perspective summarizes the features and limitations of reversible addition–
fragmentation chain transfer (RAFT) polymerization, highlighting its strengths and …

A critical appraisal of RAFT-mediated polymerization-induced self-assembly

SL Canning, GN Smith, SP Armes - Macromolecules, 2016 - ACS Publications
Recently, polymerization-induced self-assembly (PISA) has become widely recognized as a
robust and efficient route to produce block copolymer nanoparticles of controlled size …

Up in the air: oxygen tolerance in controlled/living radical polymerisation

J Yeow, R Chapman, AJ Gormley… - Chemical Society Reviews, 2018 - pubs.rsc.org
The requirement for deoxygenation in controlled/living radical polymerisation (CLRP) places
significant limitations on its widespread implementation by necessitating the use of large …

Covalent adaptable networks: smart, reconfigurable and responsive network systems

CJ Kloxin, CN Bowman - Chemical Society Reviews, 2013 - pubs.rsc.org
Covalently crosslinked materials, classically referred to as thermosets, represent a broad
class of elastic materials that readily retain their shape and molecular architecture through …

50th Anniversary Perspective: Functional Nanoparticles from the Solution Self-Assembly of Block Copolymers

U Tritschler, S Pearce, J Gwyther, GR Whittell… - …, 2017 - ACS Publications
This Perspective outlines recent advances concerning the formation and potential uses of
block copolymer micelles, a class of soft-matter-based nanoparticles of growing importance …

RAFT polymerization to form stimuli-responsive polymers

G Moad - Polymer Chemistry, 2017 - pubs.rsc.org
Stimuli-responsive polymers adapt to their surrounding environment. These polymers are
capable of responding to a variety of external stimuli, which include optical, electrical …

Living radical polymerization by the RAFT process–a third update

G Moad, E Rizzardo, SH Thang - Australian Journal of Chemistry, 2012 - CSIRO Publishing
This paper provides a third update to the review of reversible deactivation radical
polymerization (RDRP) achieved with thiocarbonylthio compounds (ZC (= S) SR) by a …

Polymeric surfactants: synthesis, properties, and links to applications

P Raffa, DAZ Wever, F Picchioni… - Chemical reviews, 2015 - ACS Publications
It is well-known that surfactants are molecules able to modify the surface properties of the
liquid in which they are introduced (usually water). The simultaneous presence of both …