Advances in non-metallocene olefin polymerization catalysis

VC Gibson, SK Spitzmesser - Chemical reviews, 2003 - ACS Publications
The field of olefin polymerization catalysis has experienced a phenomenal acceleration in
research activity over the past 5 years, with many academic and industrial research …

Design of vanadium complex catalysts for precise olefin polymerization

K Nomura, S Zhang - Chemical Reviews, 2011 - ACS Publications
Polyolefins, such as polyethylene [high-density polyethylene (HDPE), linear low-density
polyethylene (LLDPE) etc.], and polypropylene, produced by metal-catalyzed olefin …

Recent developments in vanadium-catalyzed olefin coordination polymerization

AMF Phillips, H Suo, C Maria de Fátima… - Coordination Chemistry …, 2020 - Elsevier
Polyolefins account for two thirds by weight of the global synthetic polymers. There are more
than 300 grades of commercial polyolefins, whose properties depend on their …

Synthesis and structural analysis of (imido) vanadium (V) dichloride complexes containing imidazolin-2-iminato-and imidazolidin-2-iminato ligands, and their use as …

K Nomura, BK Bahuleyan, S Zhang… - Inorganic …, 2014 - ACS Publications
A series of (imido) vanadium (V) dichloride complexes containing 1, 3-imidazolin-2-iminato
or 1, 3-imidazolidin-2-iminato ligands of the type, V (NR′) Cl2 (L)[R′= 2, 6-Me2C6H3, L …

(Imido) vanadium (V)-alkyl,-alkylidene complexes exhibiting unique reactivity towards olefins and alcohols

K Nomura, W Zhang - Chemical Science, 2010 - pubs.rsc.org
This minireview introduces recent results in the synthesis of a series of (imido) vanadium (V)-
alkyl complexes, and some reactions with alcohols (phenols) that are proposed to proceed …

Transition metal complexes bearing tridentate ligands for precise olefin polymerization

D Peng, X Yan, C Yu, S Zhang, X Li - Polymer Chemistry, 2016 - pubs.rsc.org
Tridentate chelating ligands, which possess three coordination sites and six bonding
electrons to coordinate a metal center, are considered as an alternative to the …

Polymerization of Higher α-Olefins with a Bis(Phenoxyimine)Ti Complex/i-Bu3Al/Ph3CB(C6F5)4:  Formation of Stereo- and Regioirregular High Molecular …

J Saito, Y Suzuki, H Makio, H Tanaka, M Onda… - …, 2006 - ACS Publications
The unique catalytic behavior of a bis (phenoxyimine) Ti complex combined with i-
Bu3Al/Ph3CB (C6F5) 4 (whose active species is a phenoxyamine Ti complex) is discussed …

Syntheses of Various (Arylimido) vanadium (V)–Dialkyl Complexes Containing Aryloxo and Alkoxo Ligands, and Ring-Opening Metathesis Polymerization Using a …

K Nomura, Y Onishi, M Fujiki, J Yamada - Organometallics, 2008 - ACS Publications
Treatment of V (NAr)(CH2SiMe3) 3 (1, Ar= 2, 6-Me2C6H3) with 1.0 equiv of various alcohols
in n-hexane at 25° C cleanly afforded the corresponding dialkyl complexes of the type V …

Synthesis and structural analysis of (arylimido) vanadium (V) complexes containing phenoxyimine ligands: new, efficient catalyst precursors for ethylene …

Y Onishi, S Katao, M Fujiki, K Nomura - Organometallics, 2008 - ACS Publications
A series of (arylimido) vanadium (V) complexes containing phenoxyimine ligands of the type
V (NAr) Cl2 [O-2-R-6-{(2, 6-i Pr2C6H3) N CH} C6H3][Ar= 2, 6-Me2C6H3; R= H (1a), Me …

Non-Cp type homogeneous catalytic systems for olefin polymerization

S Park, Y Han, SK Kim, J Lee, HK Kim, Y Do - Journal of organometallic …, 2004 - Elsevier
Development of homogeneous metallocene catalysts for olefin polymerization has been
briefly overviewed prior to detailed examination of the chemistry of non-Cp type …