We report a photoredox system comprising sodium iodide, triphenyl phosphine, and N, N,
N′, N′-tetramethylethylenediamine (TMEDA) that can form a self-assembled tetrameric …

We report an organophotoredox-catalyzed stereoselective allylic arylation of MBH acetates
with a palette of diaryliodonium triflates (DAIRs) to provide the corresponding trisubstituted …

Diethyl acetamidomalonate (DEAM) has been widely used for the synthesis of α-amino
acids via C-alkylation under basic conditions followed by hydrolysis/decarboxylation. In …

Broadening the scope of functionalities that can be covalently bound to single‐walled
carbon nanotubes (SWCNTs) is crucial for enhancing the versatility of this promising …

Diaryliodonium salts have become widely recognized as arylating agents in the last two
decades. Both, symmetrical and unsymmetrical forms of these salts serve as effective …

Visible‐light‐activated organic reactions unlock novel avenues for complex molecular
transformations, impossible under standard “thermal” conditions, which makes them …

We demonstrate (1) detectable halogen bonding is not critical for enabling light-driven
radical generation from diaryliodonium salts and (2) radicals generated by this route can be …

In recent times, diaryliodonium reagents (DAIRs) have witnessed a resurgence as arylating
reagents, especially under photoinduced conditions. However, reactions proceeding …

We disclose a photoredox-catalyzed arylative radical cascade between N′-arylidene-N-
acryloylhydrazides and diaryliodonium reagents to obtain the corresponding benzylated …

A metal‐and irradiation‐free approach for the direct arylation of secondary phosphines has
been developed. The reaction employs diaryliodonium salts as electrophilic aryl‐transfer …