Chemoenzymatic catalysis, by definition, involves the merging of sequential reactions using
both chemocatalysis and biocatalysis, typically in a single reaction vessel. A major …

This Review examines parts per million (ppm) palladium concentrations in catalytic cross-
coupling reactions and their relationship with mole percentage (mol%). Most studies in …

Continuous manufacturing of pharmaceuticals and fine chemicals is attractive due to its
small physical footprint, consistent product quality, and demonstrated benefits from safety …

Hierarchically porous metal-organic frameworks (H-MOFs) with micro-, meso-and
macropores have emerged as a popular class of crystalline porous materials that have …

In the last decades, cross-coupling approaches have been widely used to generate
structural diversity efficiently. Among various transition-metals, palladium has remained the …

The cross-coupling of terminal acetylenes for the construction of alkyne motives is a reaction
type that is frequently required in the assembly of pharmaceuticals and natural products that …

Many years ago, twelve principles were defined for carrying out chemical reactions and
processes from a green chemistry perspective. It is everyone's endeavor to take these points …

Designer surfactants as specific amphiphilic neutral compounds for micellar catalysis has
revolutionized metal catalysis making water a true alternative to organic solvents. In recent …

Nickel metallomicelles were formed through the self-assembly of NHC-olefin-coordinated
nickel nanoparticles and sodium dodecyl sulfate (SDS) as a surfactant in water. The …

Chemical reactions require close physical contact between reactants, catalysts, and
intermediates to proceed. In a bulk homogeneous solution, this is often governed by random …