Palladium/norbornene cooperative catalysis

J Wang, G Dong - Chemical reviews, 2019 - ACS Publications
Palladium/norbornene cooperative catalysis has emerged as a distinct approach to
construct polyfunctionalized arenes from readily available starting materials. This Review …

Transition-metal-catalyzed carbon-carbon bond formation via carbon-hydrogen bond cleavage

F Kakiuchi, T Kochi - Synthesis, 2008 - thieme-connect.com
Catalytic functionalization of unreactive CH bond has become one of the most attractive
research subjects in modern organic chemistry. To date, a variety of catalytic reactions …

C−H Activation of Phenyl Imines and 2-Phenylpyridines with [Cp*MCl2]2 (M = Ir, Rh): Regioselectivity, Kinetics, and Mechanism

L Li, WW Brennessel, WD Jones - Organometallics, 2009 - ACS Publications
Sodium acetate promoted C− H activation in a series of para-substituted phenyl imines has
been examined using [Cp* MCl2] 2 (M= Ir, Rh). The regioselectivity was investigated using a …

Microwave-assisted synthesis–catalytic applications in aqueous media

AK Rathi, MB Gawande, R Zboril, RS Varma - Coordination Chemistry …, 2015 - Elsevier
The development of sustainable methods directed towards the synthesis of molecules is due
to the heightened awareness and recognition of alternative eco-friendly and economical …

Synthesis in the Key of Catellani: Norbornene-Mediated ortho C–H Functionalization

A Martins, B Mariampillai, M Lautens - CH Activation, 2010 - Springer
In the late 1990s Catellani reported a remarkable palladium-catalyzed domino reaction [1] in
the presence of norbornene, in which aryl iodides were alkylated at the ortho positions by …

Intramolecular oxidative C− H coupling for medium-ring synthesis

DG Pintori, MF Greaney - Journal of the American Chemical …, 2011 - ACS Publications
Intramolecular Oxidative C−H Coupling for Medium-Ring Synthesis | Journal of the American
Chemical Society ACS ACS Publications C&EN CAS Find my institution Log In Journal of the …

Palladium-catalyzed acylation/alkenylation of aryl iodide: a domino approach based on the Catellani–Lautens reaction

PX Zhou, YY Ye, C Liu, LB Zhao, JY Hou… - ACS …, 2015 - ACS Publications
A new palladium-catalyzed three-component coupling involving acylation/alkenylation of
aryl iodide is reported. The reaction was carried out with readily available starting materials …

Alkylating Reagents Employed in Catellani‐Type Reactions

ZS Liu, Q Gao, HG Cheng… - Chemistry–A European …, 2018 - Wiley Online Library
The Catellani reaction is a powerful strategy that allows the expeditious synthesis of highly
substituted arenes, which are not easily accessible through traditional transition‐metal …

Transition Metal‐Free Synthesis of Sulfonyl‐ and Bromo‐Substituted Indolo[2,1‐α]isoquinoline Derivatives through Electrochemical Radical Cascade Cyclization

ZJ Shen, B Huang, N Ma, L Yao, C Yang… - Advanced Synthesis …, 2021 - Wiley Online Library
A tunable electrosynthesis of sulfonyl‐and bromo‐substituted indolo [2, 1‐α] isoquinoline
derivatives has been disclosed. In this reaction, a variety of easily available 2‐aryl‐N …

Pd-Catalyzed Chemoselective Catellani Ortho-Arylation of Iodopyrroles: Rapid Total Synthesis of Rhazinal

X Sui, R Zhu, G Li, X Ma, Z Gu - Journal of the American Chemical …, 2013 - ACS Publications
A Pd-catalyzed chemoselective Catellani reaction of iodopyrroles was developed. The rare
chemoselectivity between two different aryl halides was realized by optimizing the kinetics of …