Elastocapillarity: surface tension and the mechanics of soft solids
It is widely appreciated that surface tension can dominate the behavior of liquids at small
scales. Solids also have surface stresses of a similar magnitude, but they are usually …
scales. Solids also have surface stresses of a similar magnitude, but they are usually …
Elastocapillarity: when surface tension deforms elastic solids
Although negligible at large scales, capillary forces may become dominant for submillimetric
objects. Surface tension is usually associated with the spherical shape of small droplets and …
objects. Surface tension is usually associated with the spherical shape of small droplets and …
Poly-N-isopropylacrylamide Nanogels and Microgels at Fluid Interfaces
M Rey, MA Fernandez-Rodriguez, M Karg… - Accounts of chemical …, 2020 - ACS Publications
Conspectus The confinement of colloidal particles at liquid interfaces offers many
opportunities for materials design. Adsorption is driven by a reduction of the total free energy …
opportunities for materials design. Adsorption is driven by a reduction of the total free energy …
[HTML][HTML] Synthetic and biopolymeric microgels: Review of similarities and difference in behaviour in bulk phases and at interfaces
DZ Akgonullu, BS Murray, SD Connell, Y Fang… - Advances in Colloid and …, 2023 - Elsevier
This review discusses the current knowledge of interfacial and bulk interactions of
biopolymeric microgels in relation to the well-established properties of synthetic microgels …
biopolymeric microgels in relation to the well-established properties of synthetic microgels …
Defined core–shell particles as the key to complex interfacial self-assembly
The two-dimensional self-assembly of colloidal particles serves as a model system for
fundamental studies of structure formation and as a powerful tool to fabricate functional …
fundamental studies of structure formation and as a powerful tool to fabricate functional …
Microgels adsorbed at liquid–liquid interfaces: A joint numerical and experimental study
Soft particles display highly versatile properties with respect to hard colloids and even more
so at fluid–fluid interfaces. In particular, microgels, consisting of a cross-linked polymer …
so at fluid–fluid interfaces. In particular, microgels, consisting of a cross-linked polymer …
Hollow and core–shell microgels at oil–water interfaces: Spreading of soft particles reduces the compressibility of the monolayer
K Geisel, AA Rudov, II Potemkin, W Richtering - Langmuir, 2015 - ACS Publications
We investigate the influence of a solid core and of the cross-link density on the compression
of microgel particles at oil–water interfaces by means of compression isotherms and …
of microgel particles at oil–water interfaces by means of compression isotherms and …
Effect of the 3D swelling of microgels on their 2D phase behavior at the liquid–liquid interface
We investigate soft, temperature-sensitive microgels at fluid interfaces. Though having an
isotropic, spherical shape in bulk solution, the microgels become anisotropic upon …
isotropic, spherical shape in bulk solution, the microgels become anisotropic upon …
Stimuli-responsive behavior of PNiPAm microgels under interfacial confinement
The volume phase transition of microgels is one of the most paradigmatic examples of
stimuli-responsiveness, enabling a collapse from a highly swollen microgel state into a …
stimuli-responsiveness, enabling a collapse from a highly swollen microgel state into a …
In situ imaging of the three-dimensional shape of soft responsive particles at fluid interfaces by atomic force microscopy
The reconfiguration of individual soft and deformable particles upon adsorption at a fluid
interface underpins many aspects of their dynamics and interactions, ultimately regulating …
interface underpins many aspects of their dynamics and interactions, ultimately regulating …