Elastocapillarity: surface tension and the mechanics of soft solids

RW Style, A Jagota, CY Hui… - Annual Review of …, 2017 - annualreviews.org
It is widely appreciated that surface tension can dominate the behavior of liquids at small
scales. Solids also have surface stresses of a similar magnitude, but they are usually …

Elastocapillarity: when surface tension deforms elastic solids

J Bico, É Reyssat, B Roman - Annual Review of Fluid Mechanics, 2018 - annualreviews.org
Although negligible at large scales, capillary forces may become dominant for submillimetric
objects. Surface tension is usually associated with the spherical shape of small droplets and …

Poly-N-isopropylacrylamide Nanogels and Microgels at Fluid Interfaces

M Rey, MA Fernandez-Rodriguez, M Karg… - Accounts of chemical …, 2020 - ACS Publications
Conspectus The confinement of colloidal particles at liquid interfaces offers many
opportunities for materials design. Adsorption is driven by a reduction of the total free energy …

[HTML][HTML] Synthetic and biopolymeric microgels: Review of similarities and difference in behaviour in bulk phases and at interfaces

DZ Akgonullu, BS Murray, SD Connell, Y Fang… - Advances in Colloid and …, 2023 - Elsevier
This review discusses the current knowledge of interfacial and bulk interactions of
biopolymeric microgels in relation to the well-established properties of synthetic microgels …

Defined core–shell particles as the key to complex interfacial self-assembly

J Menath, J Eatson, R Brilmayer… - Proceedings of the …, 2021 - National Acad Sciences
The two-dimensional self-assembly of colloidal particles serves as a model system for
fundamental studies of structure formation and as a powerful tool to fabricate functional …

Microgels adsorbed at liquid–liquid interfaces: A joint numerical and experimental study

F Camerin, MA Fernández-Rodríguez, L Rovigatti… - ACS …, 2019 - ACS Publications
Soft particles display highly versatile properties with respect to hard colloids and even more
so at fluid–fluid interfaces. In particular, microgels, consisting of a cross-linked polymer …

Hollow and core–shell microgels at oil–water interfaces: Spreading of soft particles reduces the compressibility of the monolayer

K Geisel, AA Rudov, II Potemkin, W Richtering - Langmuir, 2015 - ACS Publications
We investigate the influence of a solid core and of the cross-link density on the compression
of microgel particles at oil–water interfaces by means of compression isotherms and …

Effect of the 3D swelling of microgels on their 2D phase behavior at the liquid–liquid interface

S Bochenek, A Scotti, W Ogieglo… - Langmuir, 2019 - ACS Publications
We investigate soft, temperature-sensitive microgels at fluid interfaces. Though having an
isotropic, spherical shape in bulk solution, the microgels become anisotropic upon …

Stimuli-responsive behavior of PNiPAm microgels under interfacial confinement

J Harrer, M Rey, S Ciarella, H Löwen, LMC Janssen… - Langmuir, 2019 - ACS Publications
The volume phase transition of microgels is one of the most paradigmatic examples of
stimuli-responsiveness, enabling a collapse from a highly swollen microgel state into a …

In situ imaging of the three-dimensional shape of soft responsive particles at fluid interfaces by atomic force microscopy

J Vialetto, SN Ramakrishna, L Isa - Science Advances, 2022 - science.org
The reconfiguration of individual soft and deformable particles upon adsorption at a fluid
interface underpins many aspects of their dynamics and interactions, ultimately regulating …