[HTML][HTML] Acetylene in organic synthesis: Recent progress and new uses

VV Voronin, MS Ledovskaya, AS Bogachenkov… - Molecules, 2018 - mdpi.com
Recent progress in the leading synthetic applications of acetylene is discussed from the
prospect of rapid development and novel opportunities. A diversity of reactions involving the …

Calcium‐based sustainable chemical technologies for total carbon recycling

KS Rodygin, YA Vikenteva, VP Ananikov - ChemSusChem, 2019 - Wiley Online Library
Calcium carbide, a stable solid compound composed of two atoms of carbon and one of
calcium, has proven its effectiveness in chemical synthesis, due to the safety and …

Copper-Catalyzed Construction of Benzo[4,5]imidazo[2,1-a]isoquinolines Using Calcium Carbide as a Solid Alkyne Source

H Liu, Z Li - Organic Letters, 2021 - ACS Publications
A method for the synthesis of benzo [4, 5] imidazo [2, 1-a] isoquinolines through
Sonogashira cross-coupling/nucleophilic addition tandem reactions using calcium carbide …

Calcium carbide: Versatile synthetic applications, green methodology and sustainability

KS Rodygin, MS Ledovskaya… - European Journal of …, 2021 - Wiley Online Library
Acetylene is a key building block for organic chemistry and potentially can be involved in a
diverse range of synthetic transformations. However, critical analysis of practical …

[HTML][HTML] A sustainable polymer and coating system based on renewable raw materials

JGH Hermens, T Freese, G Alachouzos, ML Lepage… - Green …, 2022 - pubs.rsc.org
Paints and coatings are widely used in modern society and their current production is mainly
dependent on the petrochemical industry. The establishment of processes using sustainable …

[3 + 2]-Cycloaddition of in Situ Generated Nitrile Imines and Acetylene for Assembling of 1,3-Disubstituted Pyrazoles with Quantitative Deuterium Labeling

VV Voronin, MS Ledovskaya, EG Gordeev… - The Journal of …, 2018 - ACS Publications
A novel synthetic methodology for the preparation of 1, 3-disubstituted pyrazoles from in situ
generated nitrile imines and acetylene is reported. The reactions are performed in a simple …

Altering Copper‐Catalyzed A3 Couplings by Mechanochemistry: One‐Pot Synthesis of 1,4‐Diamino‐2‐butynes from Aldehydes, Amines, and Calcium Carbide

M Turberg, KJ Ardila‐Fierro, C Bolm… - Angewandte Chemie …, 2018 - Wiley Online Library
The ability of mechanochemistry to alter established chemical selectivity is demonstrated. A
copper (I)‐catalyzed mechanochemical aldehyde/alkyne/amine coupling using calcium …

Biomass-and calcium carbide-based recyclable polymers

SA Metlyaeva, KS Rodygin, KA Lotsman… - Green …, 2021 - pubs.rsc.org
Biomass is a renewable source of valuable feedstock for the chemical industry of the future.
A promising approach to the utilization of valuable components of biomass is the synthesis …

Direct Synthesis of 2-Methylbenzofurans from Calcium Carbide and Salicylaldehyde p-Tosylhydrazones

R Fu, Z Li - Organic letters, 2018 - ACS Publications
A new methodology for the construction of methyl-substituted benzofuran rings from the
reactions of calcium carbide with salicylaldehyde p-tosylhydrazones/2 …

Recent advances in applications of vinyl ether monomers for precise synthesis of custom-tailored polymers

E Kirillov, K Rodygin, V Ananikov - European Polymer Journal, 2020 - Elsevier
This review highlights recent progress in the synthesis and application of vinyl ethers (VEs)
as monomers for modern homo-and co-polymerization processes. VEs can be easily …