This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

The chiral oxazoline motif is present in many ligands that have been extensively applied in a
series of important metal-catalyzed enantioselective reactions. This Review aims to provide …

Conspectus The ever-present demand for drugs with better efficacy and fewer side effects
continually motivates scientists to explore the vast chemical space. Traditionally, medicinal …

Catalytic cross-coupling reactions have had a profound impact on the synthesis of
pharmaceuticals, biologically active natural products, and materials. 1 Such reactions …

A remaining challenge in the synthetic chemistry field is formation of all-carbon quaternary
centers, a feature found in many natural products, particularly in spirocycle systems. 1 …

An efficient method for the diastereo‐and enantioselective construction of vicinal all‐carbon
quaternary stereocenters through palladium‐catalyzed decarboxylative cycloaddition of …

A stereodivergent synthesis of chiral β-lactams with contiguous tertiary/quaternary/tertiary
stereocenters has been achieved by a Cu/Ir-catalyzed three-component interrupted …

A stereodivergent synthesis of tetrahydrofuroindoles through palladium‐catalyzed
asymmetric dearomative formal [3+ 2] cycloaddition of nitroindoles with epoxybutenes was …

The success of phosphine-oxazoline ligands (PHOX) inspired the progress in P-oxazoline
ligand families by modifying either the ligand backbone, the electronic and/or steric …

An efficient method for the enantioselective construction of tertiary vinylglycols through a
palladium‐catalyzed asymmetric decarboxylative cycloaddition of vinylethylene carbonates …