Equations for the transfer of neutral molecules and ionic species from water to organic phases

MH Abraham, WE Acree Jr - The Journal of Organic Chemistry, 2010 - ACS Publications
Equations that can be used for partition coefficients of both neutral molecules and ions have
been revised, and the term that is specific to ions has been re-evaluated. A new method has …

Studies on the solvent dependence of the carbamic acid formation from ω-(1-naphthyl) alkylamines and carbon dioxide

K Masuda, Y Ito, M Horiguchi, H Fujita - Tetrahedron, 2005 - Elsevier
Carbamic acid formation from amine and carbon dioxide in a variety of solvents was
investigated by measuring NMR (1H, 13C, HMBC) and IR spectra in situ. Bubbling of CO2 …

The transfer of neutral molecules, ions and ionic species from water to ethylene glycol and to propylene carbonate; descriptors for pyridinium cations

MH Abraham, WE Acree Jr - New Journal of Chemistry, 2010 - pubs.rsc.org
Equations have been constructed for the transfer of neutral solutes from water to the solvents
ethylene glycol and propylene carbonate. These equations have been extended to include …

[HTML][HTML] Thermoswitchable catalysis to inhibit and promote plastic flow in vitrimers

F Van Lijsebetten, S Maes, JM Winne, FE Du Prez - Chemical Science, 2024 - pubs.rsc.org
Acid-base catalysis is a common strategy to induce covalent bond exchanges in dynamic
polymer networks. Strong acids or strong bases can promote rapid network rearrangements …

Energetics and structure of uranium (VI)–acetate complexes in dimethyl sulfoxide

P Di Bernardo, PL Zanonato, F Benetollo… - Inorganic …, 2012 - ACS Publications
The thermodynamics of the complexation between uranium (VI) and acetate in dimethyl
sulfoxide (DMSO) was studied at 298 K in an ionic medium of 0.1 mol dm–3 tetrabutyl …

Removal of emerging trace organic contaminants by nanofiltration and reverse osmosis

L Nghiem - 2005 - ro.uow.edu.au
This study investigates the retention mechanisms of three prominent classes of emerging
trace organic contaminants. natural steroid hormones, hormone mimicking compounds, and …

Propylene carbonate as a nonaqueous solvent for capillary electrophoresis: mobility and ionization constant of aliphatic amines

J Muzikar, T van de Goor, B Gaš… - Analytical chemistry, 2002 - ACS Publications
The two properties of aliphatic amines were investigated in propylene carbonate as solvent
that are decisive for capillary electrophoretic migration: the actual mobilities and the p K a …

Acid-base properties of phosphoric and acetic acid in aprotic organic solvents–A complete thermodynamic characterisation

D Barišić, V Tomišić, N Bregović - Analytica chimica acta, 2019 - Elsevier
Abstract Knowledge regarding the acid-base behaviour in non-aqueous media has
remained relatively scarce in spite of its importance for many aspects of chemistry. The …

Electrochemical Proton Reduction and Equilibrium Acidity (pKa) in Aprotic Ionic Liquids: Phenols, Carboxylic Acids, and Sulfonic Acids

CL Bentley, AM Bond, AF Hollenkamp… - The Journal of …, 2015 - ACS Publications
Many organic compounds contain acidic and/or basic functional groups that dictate their
physical, chemical, and biological properties. For this reason, the acid dissociation constant …

Acidic‐basic properties of three alanine‐based peptides containing acidic and basic side chains: Comparison between theory and experiment

J Makowska, K Bagińska, A Liwo… - Peptide …, 2008 - Wiley Online Library
The purpose of this work was to evaluate the effect of the nature of the ionizable end groups,
and the solvent, on their acid‐base properties in alanine‐based peptides. Hence, the acid …