An enantiomerically enriched 3-hydroxymethyl pentenal unit is one of the key structural
cores in plenty of natural products and drug candidates with significant biological activities …

In the current scenario, green technologies in chemistry and various fields create attention to
every researcher. The green synthesis provides environmentally and eco-friendly raw …

This study developed a method of synthesizing distal amino acid derivatives by the ring‐
opening reaction of cyclic ketones, following the amino esterification functionalization of both …

Chemoselective α-acylation of tertiary amides proceeded with highly electrophilic acid
anhydrides and weak bases under mild conditions. β-Ketoamides containing trifluoroacetyl …

The enantioselective [3+ 1]-cycloaddition of two structurally different diazo compounds has
been achieved using chiral bisoxazoline copper (I) complexes as a catalyst, providing a …

Cycloaddition of metallo‐vinylcarbenes is an intramolecular combination of the three carbon
atoms of a metal vinylcarbene with the carbon of a carbenoid donor or the nitrogen of a …

Trisubstituted donor–acceptor cyclopropenes (DACPs) generated in situ from enoldiazo
compounds react with nucleophiles to form α‐substituted succinic acid derivatives in high …