Probing transient molecular structures in photochemical processes using laser-initiated time-resolved X-ray absorption spectroscopy

LX Chen - Annu. Rev. Phys. Chem., 2005 - annualreviews.org
▪ Abstract Molecular structures during chemical processes are crucial for predicting
molecular reactivity and reaction mechanisms. Using a laser pulse as an internal clock for …

Exciplex quenching of photoexcited platinum (II) terpyridines: influence of the orbital parentage

DKC Tears, DR McMillin - Coordination Chemistry Reviews, 2001 - Elsevier
Quenching studies involving a range of Lewis bases establish that exciplex quenching can
affect the lifetime of the emissive charge-transfer state of a platinum (II) terpyridine. The …

Picosecond to microsecond photodynamics of a nonplanar nickel porphyrin: solvent dielectric and temperature effects

CM Drain, S Gentemann, JA Roberts… - Journal of the …, 1998 - ACS Publications
The lifetime of the (dz 2, dx 2-y 2) metal excited state of nickel (II) 5, 10, 15, 20-tetra-tert-
butylporphyrin (NiT (t-Bu) P) exhibits an extraordinary dependence on solvent dielectric …

Understanding binding interactions of cationic porphyrins with B-form DNA

DR McMillin, AH Shelton, SA Bejune… - Coordination chemistry …, 2005 - Elsevier
The DNA-binding interactions of 5, 10, 15, 20-tetra (N-methylpyridinium-4-yl) porphyrin,
herein denoted H2T4, and related cationic porphyrins have long been of interest because of …

Excited-state molecular structures captured by X-ray transient absorption spectroscopy: a decade and beyond

LX Chen, X Zhang, JV Lockard, AB Stickrath… - … A: Foundations of …, 2010 - scripts.iucr.org
Transient molecular structures along chemical reaction pathways are important for
predicting molecular reactivity, understanding reaction mechanisms, as well as controlling …

EPR spectra, luminescence data, and radiationless decay processes of copper (II) porphyrins

KL Cunningham, KM McNett, RA Pierce… - Inorganic …, 1997 - ACS Publications
For a series of copper (II) porphyrins, we report EPR data from solid solutions as well as E 0
values for the first ring oxidation, emission spectra, and luminescence lifetimes in methylene …

Photocatalytic activity of Hemin (Fe (III) porphyrin) anchored BaTiO 3 under the illumination of visible light: Synergetic effects of photosensitization, photo-Fenton & …

LG Devi, PM Nithya - Inorganic Chemistry Frontiers, 2018 - pubs.rsc.org
The photocatalytic activity of Hemin (Fe (III) porphyrin) anchored BaTiO3 (HBTO) under the
illumination of visible light was studied. The average crystallite sizes obtained from PXRD …

Intramolecular vibrational energy redistribution and intermolecular energy transfer in the excited state of nickel octaethylporphyrin

Y Mizutani, Y Uesugi, T Kitagawa - The Journal of chemical physics, 1999 - pubs.aip.org
The formation of a vibrationally excited photoproduct of nickel octaethylporphyrin (NiOEP)
upon (π, π*) excitation and its subsequent vibrational energy relaxation were monitored by …

The impact of central metal ions in Porphyrin functionalized ZnO/TiO2 for enhanced solar energy conversion

S Sardar, P Kar, SK Pal - Journal of Materials NanoScience, 2014 - pubs.thesciencein.org
The photochemistry of porphyrins and metalloporphyrins has drawn immense research
interest because of their diverse catalytic activity and biological relevance. Porphyrin …

Impact of Metal Ions in Porphyrin‐Based Applied Materials for Visible‐Light Photocatalysis: Key Information from Ultrafast Electronic Spectroscopy

P Kar, S Sardar, E Alarousu, J Sun… - … A European Journal, 2014 - Wiley Online Library
Protoporphyrin IX‐zinc oxide (PP‐ZnO) nanohybrids have been synthesized for applications
in photocatalytic devices. High‐resolution transmission electron microscopy (HRTEM), X‐ray …