Dinuclear metal complexes: multifunctional properties and applications

G Li, D Zhu, X Wang, Z Su, MR Bryce - Chemical Society Reviews, 2020 - pubs.rsc.org
The development of metal complexes for optoelectronic applications is a fertile area of
research. In contrast to the rigorous development of mononuclear metal complexes …

Cyclometalated Ir (III) complexes towards blue-emissive dopant for organic light-emitting diodes: fundamentals of photophysics and designing strategies

S Lee, WS Han - Inorganic Chemistry Frontiers, 2020 - pubs.rsc.org
The main difficulties hindering development of a deep-blue phosphorescent cyclometalated
Ir (III) complex are insufficient colour purity, ie, failure to achieve ideal Commission …

Recent advances in synthesis of molecular heteroleptic osmium and iridium phosphorescent emitters

ML Buil, MA Esteruelas… - European journal of …, 2021 - Wiley Online Library
The application of new procedures of organometallic synthesis based on alternative starting
complexes has given rise to a significant enhancement in the preparation of osmium (IV) …

Exploring a Mitochondria Targeting, Dinuclear Cyclometalated Iridium (III) Complex for Image-Guided Photodynamic Therapy in Triple-Negative Breast Cancer Cells

N Neelambaran, S Shamjith, VP Murali… - ACS Applied Bio …, 2023 - ACS Publications
Photodynamic therapy (PDT) has emerged as an efficient and noninvasive treatment
approach utilizing laser-triggered photosensitizers for combating cancer. Within this rapidly …

Recent advances in luminescent dinuclear iridium (III) complexes and their application in organic electroluminescent devices

G Li, DG Congrave, D Zhu, Z Su, MR Bryce - Polyhedron, 2018 - Elsevier
In contrast to mononuclear iridium (III) complexes, dinuclear iridium (III) complexes have
been less well studied, especially as dopants in phosphorescent organic light-emitting …

Bis-heteroleptic cationic iridium (III) complexes featuring cyclometalating 2-phenylbenzimidazole ligands: a combined experimental and theoretical study

E Martìnez-Vollbert, C Ciambrone… - Inorganic …, 2022 - ACS Publications
In this report, we investigate a new family of cationic iridium (III) complexes featuring the
cyclometalating ligand 2-phenylbenzimidazole and ancillary ligand 4, 4′-dimethyl-2, 2 …

Photoluminescence of cyclometalated iridium complexes in poly (methyl methacrylate) films

H Na, PN Lai, LM Cañada, TS Teets - Organometallics, 2018 - ACS Publications
In this work, we describe the emission properties of 12 heteroleptic bis-cyclometalated
iridium complexes immobilized in poly (methyl methacrylate)(PMMA) thin films. The …

Luminescent diiridium complexes with bridging pyrazolates: Characterization and fabrication of OLEDs using vacuum thermal deposition

JL Liao, P Rajakannu, P Gnanasekaran… - Advanced Optical …, 2018 - Wiley Online Library
A series of novel diiridium complexes (1–4) bearing both functional 2‐pyrazolyl‐6‐phenyl
pyridine chelate and bidentate phenyl imidazolylidene chelate are synthesized, for which …

Single-molecule microRNA electrochemiluminescence detection using cyclometalated dinuclear Ir (III) complex with synergistic effect

TB Gao, JJ Zhang, J Wen, XX Yang, H Ma… - Analytical …, 2019 - ACS Publications
The realization of electrochemiluminescence (ECL) detection at the single-molecule level is
a longstanding goal of ECL assay that requires a novel ECL probe with significantly …

Bromination and C–C Cross-Coupling Reactions for the C–H Functionalization of Iridium (III) Emitters

PLT Boudreault, MA Esteruelas, E Mora, E Onate… - …, 2021 - ACS Publications
The orthometalated phenyl groups of the dimer [Ir (μ-Cl){κ2-C, N-(C6H3Me-py)} 2] 2 have
been selectively brominated, at para-position with regard to the Ir–C bonds, with N …