Beyond a solvent: triple roles of dimethylformamide in organic chemistry

MM Heravi, M Ghavidel, L Mohammadkhani - RSC advances, 2018 - pubs.rsc.org
N, N-Dimethylformamide (DMF) is frequently used as an aprotic solvent in chemical
transformations in laboratories of academia as well as in those of chemical industry. In the …

C–CN bond formation: an overview of diverse strategies

S Pimparkar, A Koodan, S Maiti, NS Ahmed… - Chemical …, 2021 - pubs.rsc.org
Nitrile or cyano compounds are an important part of structural motifs in dyes, agrochemicals,
medicinal compounds, and electronic materials. Also, aryl nitrile is an important intermediate …

Enhancement of catalytic detoxification of polycyclic aromatic hydrocarbons in fly ash from municipal solid waste incineration via magnetic hydroxyapatite-assisted …

D Shi, J Liu, H Tong, K Fu, M Salam, J Huang… - Science of The Total …, 2024 - Elsevier
The emission of carcinogenic, teratogenic, and mutagenic polycyclic aromatic hydrocarbons
(PAHs) during municipal solid waste incineration (MSWI) of fly ash (FA) has attracted …

Light hydrocarbon conversion to acrylonitrile and acetonitrile–a review

K Trangwachirachai, YC Lin - Dalton Transactions, 2023 - pubs.rsc.org
Nitriles, particularly acrylonitrile and acetonitrile, are versatile chemicals that are used in
various fields, such as polymer synthesis and pharmaceutical production. For a long time …

N, N-Dimethylformamide (DMF): An Inexpensive and Attractive Reactant

X Cai, H Guo - Current Organic Chemistry, 2021 - ingentaconnect.com
The development of simple, atom-economical, and sustainable methodologies for the
construction of various functional molecules from easily available substrates has been of …

An insight on the influence of surface Lewis acid sites for regioselective CH bond C3-cyanation of indole using NH4I and DMF as combined cyanide source over Cu …

V Boosa, V Bilakanti, VK Velisoju, N Gutta, S Inkollu… - Molecular …, 2018 - Elsevier
The Cu dispersed on mesoporous SBA-15 has demonstrated the regioselective Csingle
bondH bond C 3-cyanation of indoles by in-situ generation of single bondCN using DMF …

Copper Mediated Chemo‐and Stereoselective Cyanation Reactions

P Chandra, N Choudhary, GK Lahiri… - Asian Journal of …, 2021 - Wiley Online Library
Earth‐abundant transition metal based catalytic materials can become pivotal for clean
chemical manufacturing due to their facile handling and air moisture stability replacing …

Synthesis of 1H-benzimidazoles via the condensation of o-phenylenediamines with DMF promoted by organic acid under microwave irradiation

W Li, X Li, H Hong, R Xie, N Zhu - Synthetic Communications, 2024 - Taylor & Francis
An effective, green and eco-friendly method was developed to synthesize 1 H-
benzimidazole under microwave irradiation. The reactions of substituted o …

Cu (OAc) 2-Mediated benzimidazole-directed C–H cyanation using 2-(4-methylpiperazin-1-yl) acetonitrile as the cyano source

T Zhang, J Qiao, H Song, F Xu, X Liu, C Xu… - New Journal of …, 2019 - pubs.rsc.org
A new protocol for the Cu (OAc) 2-mediated cyanation of arenes using benzimidazole as the
directing group with 2-(4-methylpiperazin-1-yl) acetonitrile as the cyano source was …

Role of Surface Basic Sites in Sonogashira Coupling Reaction over Ca5(PO4)3OH Supported Pd Catalyst: Investigation by Diffuse Reflectance Infrared Fourier …

V Bilakanti, V Boosa, VK Velisoju, N Gutta… - The Journal of …, 2017 - ACS Publications
Hydroxyapatite [Ca5 (PO4) 3 (OH); HAP] supported Pd catalyst has been identified as an
efficient and reusable heterogeneous catalyst for the Sonogashira coupling reaction under …