Glyme-based electrolytes: suitable solutions for next-generation lithium batteries
The concept of green in a battery involves the chemical nature of electrodes and electrolytes
as well as the economic sustainability of the cell. Although these aspects are typically …
as well as the economic sustainability of the cell. Although these aspects are typically …
A review of solvate ionic liquids: Physical parameters and synthetic applications
DJ Eyckens, LC Henderson - Frontiers in chemistry, 2019 - frontiersin.org
Solvate Ionic Liquids (SILs) are a relatively new class of ionic liquids consisting of a
coordinating solvent and salt, that give rise to a chelate complex with very similar properties …
coordinating solvent and salt, that give rise to a chelate complex with very similar properties …
A simple approach for making a viable, safe, and high-performances lithium-sulfur battery
L Carbone, T Coneglian, M Gobet, S Munoz… - Journal of Power …, 2018 - Elsevier
We report an electrolyte with low flammability, based on diethylene glycol dimethyl ether
(DEGDME) dissolving lithium bis-trifluoromethane sulfonimidate (LiTFSI), and lithium nitrate …
(DEGDME) dissolving lithium bis-trifluoromethane sulfonimidate (LiTFSI), and lithium nitrate …
Structure and dynamics of polysulfide clusters in a nonaqueous solvent mixture of 1, 3-dioxolane and 1, 2-dimethoxyethane
Molecular clustering and associated dynamic processes of lithium polysulfide species were
unraveled using classical molecular dynamics and ab initio metadynamics calculations. The …
unraveled using classical molecular dynamics and ab initio metadynamics calculations. The …
NMR Methodology for Measuring Dissolved O2 and Transport in Lithium–Air Batteries
Similar to fuel cells, poor mass transport of redox active species, such as dissolved oxygen
gas, is one of the challenges faced by lithium–air batteries (LABs). Capitalizing on the …
gas, is one of the challenges faced by lithium–air batteries (LABs). Capitalizing on the …
Solvate cation migration and ion correlations in solvate ionic liquids
F Schmidt, M Schönhoff - The Journal of Physical Chemistry B, 2020 - ACS Publications
Lithium salt–glyme mixtures are interesting candidates as electrolytes for battery
applications. Depending on the type of glyme or anion and the salt concentration, they either …
applications. Depending on the type of glyme or anion and the salt concentration, they either …
Ion transport and association study of glyme-based electrolytes with lithium and sodium salts
Glyme solvents are a promising avenue of research in novel electrolytes, due to their
thermal and chemical stability, large electrochemical window, and tunable properties. This …
thermal and chemical stability, large electrochemical window, and tunable properties. This …
Quantifying dissolved transition metals in battery electrolyte solutions with NMR paramagnetic relaxation enhancement
Transition metal dissolution is an important contributor to capacity fade in lithium-ion cells.
NMR relaxation rates are proportional to the concentration of paramagnetic species, making …
NMR relaxation rates are proportional to the concentration of paramagnetic species, making …
Solvation structure of sodium bis (fluorosulfonyl) imide-glyme solvate ionic liquids and its influence on cycling of Na-MNC cathodes
P Geysens, VS Rangasamy… - The Journal of …, 2018 - ACS Publications
Electrolytes consisting of sodium bis (fluorosulfonyl) imide (NaFSI) dissolved in glymes
(monoglyme, diglyme, and triglyme) were characterized by FT-Raman spectroscopy and …
(monoglyme, diglyme, and triglyme) were characterized by FT-Raman spectroscopy and …
Nuclear magnetic resonance characterisation of ionic liquids and organic ionic plastic crystals: common approaches and recent advances
H Zhu, LA O'Dell - Chemical Communications, 2021 - pubs.rsc.org
Ionic liquids, and their solid-state equivalents organic ionic plastic crystals, show many
useful and tailorable properties that make them interesting for a wide range of applications …
useful and tailorable properties that make them interesting for a wide range of applications …