Carbenes and nitrenes can exist in both singlet and triplet states, sometimes equally stable
and interconverting either thermally or photochemically. Many carbene and nitrene reactions …

Aromatic polyazides are widely used as starting materials in organic synthesis and
photochemical studies, as well as photoresists in microelectronics and as cross-linking …

Stable monocoordinated organobismuthinidenes were only recently isolated and analyzed
toward their chemical and electronic structure. Quantum chemical calculations on t Bu …

Abstract Among all C‐, N‐, and O‐centered polyradicals, high‐spin nitrenes possess the
largest magnetic anisotropy and are of considerable interest as multi‐level molecular spin …

Low‐temperature UV‐photolysis of mesitylphosphiranes under highly anaerobic conditions
leads to the formation of the triplet mesitylphosphinidene (MesP). The recorded X‐band EPR …

The septet ground state trinitrenes 1, 3, 5‐trichloro‐2, 4, 6‐trinitrenobenzene and 1, 3, 5‐
tribromo‐2, 4, 6‐trinitrenobenzene were isolated in inert (Ar, Ne, and Xe) as well as reactive …

Experimental and theoretical studies on aromatic nitrenes bearing from three to six unpaired
electrons and having quartet, quintet, sextet or septet ground spin states, published in the …

The first X‐band EPR spectrum containing only non‐overlapping signals of septet pyridyl‐2,
4, 6‐trinitrene and triplet pyridylnitrenes is reported. This spectrum was recorded after …

Carbene und Nitrene können sowohl in Singulett‐als auch Triplett‐Zuständen existieren, die
zuweilen gleich stabil sind und entweder thermisch oder photochemisch interkonvertiert …

We report on W-band EPR and quantum chemical investigation of novel organic
tetraradicals with negative axial zero-field splitting (ZFS) parameter D. These belong to the …