Organic chemistry on solid surfaces
Z Ma, F Zaera - Surface science reports, 2006 - Elsevier
Chemistry on solid surfaces is central to many areas of practical interest such as
heterogeneous catalysis, tribology, electrochemistry, and materials processing. With the …
heterogeneous catalysis, tribology, electrochemistry, and materials processing. With the …
Mechanism of Methanol Synthesis on Cu through CO2 and CO Hydrogenation
LC Grabow, M Mavrikakis - Acs Catalysis, 2011 - ACS Publications
We present a comprehensive mean-field microkinetic model for the methanol synthesis and
water-gas-shift (WGS) reactions that includes novel reaction intermediates, such as formic …
water-gas-shift (WGS) reactions that includes novel reaction intermediates, such as formic …
Catalyst Selection over an Electrochemical Reductive Coupling Reaction toward Direct Electrosynthesis of Oxime from NOx and Aldehyde
Aqueous electrochemical coupling reactions, which enable the green synthesis of complex
organic compounds, will be a crucial tool in synthetic chemistry. However, a lack of informed …
organic compounds, will be a crucial tool in synthetic chemistry. However, a lack of informed …
Methanol decomposition on Cu (111): a DFT study
J Greeley, M Mavrikakis - Journal of Catalysis, 2002 - Elsevier
Self-consistent periodic DFT–GGA calculations are used to investigate the methanol
decomposition pathway on both equilibrium and stretched Cu (111) surfaces. The …
decomposition pathway on both equilibrium and stretched Cu (111) surfaces. The …
Water co-catalyzed selective dehydrogenation of methanol to formaldehyde and hydrogen
The non-oxidative dehydrogenation of methanol to formaldehyde is considered a promising
method to produce formaldehyde and clean hydrogen gas. Although Cu-based catalysts …
method to produce formaldehyde and clean hydrogen gas. Although Cu-based catalysts …
Model studies with gold: a versatile oxidation and hydrogenation catalyst
Historically, scientists have considered gold an inert catalyst constituent. However, in recent
decades, chemists have discovered that nanoscale gold shows exceptional activity for many …
decades, chemists have discovered that nanoscale gold shows exceptional activity for many …
Molecular-scale perspective of water-catalyzed methanol dehydrogenation to formaldehyde
MB Boucher, MD Marcinkowski, ML Liriano… - ACS …, 2013 - ACS Publications
Methanol steam reforming is a promising reaction for on-demand hydrogen production.
Copper catalysts have excellent activity and selectivity for methanol conversion to hydrogen …
Copper catalysts have excellent activity and selectivity for methanol conversion to hydrogen …
Surface structure dependence of the dry dehydrogenation of alcohols on Cu (111) and Cu (110)
The non-oxidative dehydrogenation of alcohols is considered as an important method to
produce aldehydes for the chemical industry and hydrogen gas. However, current industrial …
produce aldehydes for the chemical industry and hydrogen gas. However, current industrial …
Ethanol Decomposition: C C Cleavage Selectivity on Rh (111)
Ethanol adsorption, desorption and decomposition on Rh (111) have been studied by X‐ray
photoelectron spectroscopy and temperature‐programmed desorption experiments. The …
photoelectron spectroscopy and temperature‐programmed desorption experiments. The …
Carbon− carbon bond formation on model titanium oxide surfaces: identification of surface reaction intermediates by high-resolution electron energy loss spectroscopy
The interaction of CH2O with perfect and defective TiO2 (110) surfaces (produced by
overannealing and Ar ion sputtering methods) was studied by thermal desorption …
overannealing and Ar ion sputtering methods) was studied by thermal desorption …