Structure‐Sensitivity and Electrolyte Effects in CO2 Electroreduction: From Model Studies to Applications

P Sebastián‐Pascual, S Mezzavilla… - …, 2019 - Wiley Online Library
Aiming to reduce anthropogenic CO2 emissions, there is an urgent demand to develop more
efficient and affordable technologies which convert CO2 into valuable feedstock molecules …

Interfacial water reorganization as a pH-dependent descriptor of the hydrogen evolution rate on platinum electrodes

I Ledezma-Yanez, WDZ Wallace, P Sebastián-Pascual… - Nature Energy, 2017 - nature.com
Hydrogen evolution on platinum is a key reaction for electrocatalysis and sustainable energy
storage, yet its pH-dependent kinetics are not fully understood. Here we present a detailed …

On the electrode charge at the metal/solution interface with specific adsorption

MK Zhang, J Cai, YX Chen - Current Opinion in Electrochemistry, 2022 - Elsevier
The electrode charge is one of the most fundamental concepts in electrochemistry. However,
ambiguousness often comes to its definition as specific adsorption occurs. In this review …

In Situ Monitoring Using ATR-SEIRAS of the Electrocatalytic Reduction of CO2 on Au in an Ionic Liquid/Water Mixture

M Papasizza, A Cuesta - ACS Catalysis, 2018 - ACS Publications
The electrochemical reduction of CO2 to CO in ionic liquids and ionic-liquid/water mixtures
has received considerable attention due to recent claims of extraordinarily high energy …

Studies of electrochemical interfaces by broadband sum frequency generation

NG Rey, DD Dlott - Journal of Electroanalytical Chemistry, 2017 - Elsevier
We present a perspective on the use of potential-dependent broadband multiplex vibrational
sum-frequency generation spectroscopy (hereafter SFG) to study electrochemical systems …

The electric double layer in an ionic liquid incorporated with water molecules: atomic force microscopy force curve study

Y Zhong, J Yan, M Li, L Chen, B Mao - ChemElectroChem, 2016 - Wiley Online Library
Electrochemical techniques and atomic force microscopy based force curve measurements
under potential control are combined to investigate the effect of small amounts of water on …

Three-dimensional nucleation with diffusion controlled growth: A comparative study of electrochemical phase formation from aqueous and deep eutectic solvents

P Sebastián, LE Botello, E Vallés, E Gómez… - Journal of …, 2017 - Elsevier
The nucleation of Ag onto vitreous carbon from aqueous 3 M NaCl or 0.6 M NaClO 4 and
deep eutectic solvent (DES) 1: 2 M mixture of choline chloride: urea solutions containing …

In-situ STM and AFM Studies on Electrochemical Interfaces in imidazolium-based ionic liquids

S Liu, J Peng, L Chen, P Sebastian, JM Feliu, J Yan… - Electrochimica …, 2019 - Elsevier
Voltammetric responses, adsorption behaviors and layered structures of 1-ethyl-2, 3-
dimethylimidazolium bis (trifluoromethylsulfonyl) imide (EMMITFSI) and 1-ethyl-3 …

Surface electrochemistry with Pt single‐crystal electrodes

V Climent, JM Feliu - Advances in Electrochemical Science and …, 2017 - Wiley Online Library
The extensive knowledge gained with the study of single‐crystal electrodes about the
influence of surface structure on the electrochemical properties of platinum (Pt) has proved …

Pt (hkl) surface charge and reactivity

V Briega-Martos, E Herrero, JM Feliu - Current Opinion in Electrochemistry, 2019 - Elsevier
Interfacial charge has a decisive influence on the reactivity of the most common
electrochemical reactions for practical applications. In this work, the concepts of surface …