This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

The chiral oxazoline motif is present in many ligands that have been extensively applied in a
series of important metal-catalyzed enantioselective reactions. This Review aims to provide …

The asymmetric alkylation of enolates is a particularly versatile method for the construction
of α-stereogenic carbonyl motifs, which are ubiquitous in synthetic chemistry. Over the past …

Stereoconvergent catalysis is an important subset of asymmetric synthesis that
encompasses stereoablative transformations, dynamic kinetic resolutions, and dynamic …

The worldwide urge to embrace a sustainable and bio-compatible chemistry has led industry
and academia to develop of chlorine-free methodologies focused on the use of CO2 and …

Herein, we report a multistep one-pot reaction of substituted pyridines leading to N-protected
tetrahydropyridines with outstanding enantioselectivity (up to 97% ee). An iridium (I) …

Defluorinative manipulation of polyfluorinated molecules has shown great promise due to its
granting of synthetic versatility to inert C− F bonds. The development of chemo‐, stereo‐and …

Over the past 20 years, the asymmetric synthesis of acyclic tetrasubstituted stereocenters by
Pd-catalyzed asymmetric allylic alkylation (Pd-AAA) strategies has seen considerable …

Covering: up to the end of 2017 Enantioselective Pd-catalyzed allylic alkylations of prochiral
enolates represent a powerful tool for the construction of all-carbon quaternary …

The palladium‐catalyzed decarboxylative asymmetric allylic alkylation (DAAA) is
comprehensively reviewed, from its original development to recent advances in terms of …