Chemical expansion: implications for electrochemical energy storage and conversion devices

SR Bishop, D Marrocchelli… - Annual Review of …, 2014 - annualreviews.org
Many energy-related materials rely on the uptake and release of large quantities of ions, for
example, Li+ in batteries, H+ in hydrogen storage materials, and O2− in solid-oxide fuel cell …

Revisiting ionic conductivity of rare earth doped ceria: Dependency on different factors

SK Anirban, A Dutta - International Journal of Hydrogen Energy, 2020 - Elsevier
The rare–earth–doped ceria overcomes the difficulties of yttria–stabilized zirconia (YSZ) as
an electrolyte in Solid Oxide Fuel Cells (SOFCs) due to its superior ionic conductivity in the …

Revisiting the temperature dependent ionic conductivity of yttria stabilized zirconia (YSZ)

C Ahamer, AK Opitz, GM Rupp… - Journal of The …, 2017 - iopscience.iop.org
The temperature dependent conductivity of yttria stabilized zirconia (YSZ) exhibits a bending
in Arrhenius' plots which is frequently discussed in terms of free and associated oxygen …

Tuning Ionic Conductivity in Fluorite Gd-Doped CeO2-Bixbyite RE2O3 (RE = Y and Sm) Multilayer Thin Films by Controlling Interfacial Strain

G Yang, M El Loubani, HR Chalaki, J Kim… - ACS Applied …, 2023 - ACS Publications
Interfacial strain in heteroepitaxial oxide thin films is a powerful tool for discovering
properties and recognizing the potential of materials performance. Particularly, facilitating …

Structural features of Sm-and Gd-doped ceria studied by synchrotron X-ray diffraction and μ-Raman spectroscopy

C Artini, M Pani, MM Carnasciali, MT Buscaglia… - Inorganic …, 2015 - ACS Publications
A structural study of Sm-and Gd-doped ceria was performed with the aim to clarify some
unexplained structural features.(Ce1–x RE x) O2–x/2 samples (RE≡ Sm, Gd; x= 0, 0.1,..., 1) …

Defect chemistry and lithium transport in Li 3 OCl anti-perovskite superionic conductors

Z Lu, C Chen, ZM Baiyee, X Chen, C Niu… - Physical Chemistry …, 2015 - pubs.rsc.org
Lithium-rich anti-perovskites (LiRAPs) are a promising family of solid electrolytes, which
exhibit ionic conductivities above 10− 3 S cm− 1 at room temperature, among the highest …

Rare-earth-doped ceria systems and their performance as solid electrolytes: A puzzling tangle of structural issues at the average and local scale

C Artini - Inorganic Chemistry, 2018 - ACS Publications
Rare-earth (RE)-doped ceria systems, in particular when RE≡ Nd, Sm, or Gd, are well-
known to be characterized by high values of ionic conductivity in the intermediate …

Ceria co-doping: synergistic or average effect?

M Burbano, S Nadin, D Marrocchelli… - Physical Chemistry …, 2014 - pubs.rsc.org
Ceria (CeO2) co-doping has been suggested as a means to achieve ionic conductivities that
are significantly higher than those in singly doped systems. Rekindled interest in this topic …

Scalable oxygen‐ion transport kinetics in metal‐oxide films: impact of thermally induced lattice compaction in acceptor doped ceria films

JLM Rupp, E Fabbri, D Marrocchelli… - Advanced Functional …, 2014 - Wiley Online Library
In this paper, we focus on the effect of processing‐dependent lattice strain on oxygen ion
conductivity in ceria based solid electrolyte thin films. This is of importance for technological …

Probing Complex Disorder in Ce1-xGdxO2-x/2 Using the Pair Distribution Function Analysis

M Scavini, M Coduri, M Allieta, M Brunelli… - Chemistry of …, 2012 - ACS Publications
In this work the first Pair Distribution Function (PDF) study on Ce1-x Gd x O2-x/2 (CGO)
electrolytes for solid oxide fuel cells is presented, aiming to unveil the complex positional …