Transition metal-catalyzed C–H amination: scope, mechanism, and applications

Y Park, Y Kim, S Chang - Chemical reviews, 2017 - ACS Publications
Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient
synthetic approach to construct N-functionalized molecules. Over the last few decades …

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

Z Chen, B Wang, J Zhang, W Yu, Z Liu… - Organic Chemistry …, 2015 - pubs.rsc.org
Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

Carboxylate-assisted ruthenium-catalyzed alkyne annulations by C–H/Het–H bond functionalizations

L Ackermann - Accounts of Chemical Research, 2014 - ACS Publications
To improve the atom-and step-economy of organic syntheses, researchers would like to
capitalize upon the chemistry of otherwise inert carbon–hydrogen (C–H) bonds. During the …

Carboxylate-assisted transition-metal-catalyzed C− H bond functionalizations: mechanism and scope

L Ackermann - Chemical reviews, 2011 - ACS Publications
The site-selective formation of carbonrcarbon bonds through direct functionalizations of
otherwise unreactive carbonrhydrogen bonds constitutes an economically attractive strategy …

Transition metal-mediated synthesis of monocyclic aromatic heterocycles

AV Gulevich, AS Dudnik, N Chernyak… - Chemical …, 2013 - ACS Publications
Transition Metal-Mediated Synthesis of Monocyclic Aromatic Heterocycles | Chemical Reviews
ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS …

Towards mild metal-catalyzed C–H bond activation

J Wencel-Delord, T Dröge, F Liu… - Chemical Society Reviews, 2011 - pubs.rsc.org
Functionalizing traditionally inert carbon–hydrogen bonds represents a powerful
transformation in organic synthesis, providing new entries to valuable structural motifs and …

Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

SH Cho, JY Kim, J Kwak, S Chang - Chemical Society Reviews, 2011 - pubs.rsc.org
The direct functionalization of heterocyclic compounds has emerged as one of the most
important topics in the field of metal-catalyzed C–H bond activation due to the fact that …

Formal SN‐Type Reactions in Rhodium(III)‐Catalyzed CH Bond Activation

N Kuhl, N Schröder, F Glorius - Advanced Synthesis & Catalysis, 2014 - Wiley Online Library
Abstract (Pentamethylcyclopentadienyl) rhodium (RhCp*)‐catalyzed C H transformations
have emerged as a prosperous field in C H bond activation. Recent advances in this area …

Palladium-catalyzed ligand-directed C− H functionalization reactions

TW Lyons, MS Sanford - Chemical reviews, 2010 - ACS Publications
The development of methods for the direct conversion of carbonshydrogen bonds into
carbon-oxygen, carbon-halogen, carbon-nitrogen, carbon-sulfur, and carbon-carbon bonds …

Recent advances in directed C–H functionalizations using monodentate nitrogen-based directing groups

M Zhang, Y Zhang, X Jie, H Zhao, G Li… - Organic Chemistry …, 2014 - pubs.rsc.org
The use of directing groups has proven to be a successful strategy to enhance reactivity and
control selectivity in C–H functionalization reactions. In the past decade, a multitude of new …