Sixty years of the van der Waals and Platteeuw model for clathrate hydrates—A critical review from its statistical thermodynamic basis to its extensions and …

FDA Medeiros, ISV Segtovich, FW Tavares… - Chemical …, 2020 - ACS Publications
In light of the 60-year anniversary of the publishing of “Clathrate Solutions” by van der Waals
and Platteeuw in 2019, we present a critical review of the famed solid solution model first …

Patel-Teja cubic equation of state–A review of modifications and applications till 2022

PNP Ghoderao, M Narayan, VH Dalvi, HS Byun - Fluid Phase Equilibria, 2023 - Elsevier
Abstract The Patel-Teja equation of state (PT EOS) is extensively researched, modified, and
applied three-parameter cubic equation of state for the prediction of volumetric and …

Carbon dioxide hydrate growth dynamics and crystallography in pure and saline water

HJ Dongre, N Thakre, AV Palodkar… - Crystal Growth & …, 2020 - ACS Publications
To develop the crucial concepts of clathrate hydrates toward the hydrate-based
technological implications, it is indispensable to comprehend their formation and growth …

Microscopic molecular insights into hydrate formation and growth in pure and saline water environments

N Thakre, AV Palodkar, HJ Dongre… - The Journal of Physical …, 2020 - ACS Publications
The growth dynamics of natural gas hydrates in saline water has been studied using
copious experiments and spectroscopic observations; however, the microscopic evidences …

Physical and molecular insights to Clathrate hydrate thermodynamics

N Thakre, AK Jana - Renewable and Sustainable Energy Reviews, 2021 - Elsevier
Clathrate hydrate forms by a combination of water and gas/liquid organic molecules in
favorable conditions of relatively low temperature and high pressure. The compound gained …

Proposing crystallographic theory to deparameterize hydrate phase description: Physical insights and validation

HJ Dongre, AK Jana - Industrial & Engineering Chemistry …, 2023 - ACS Publications
This work offers to resolve a crucial issue that has persisted for the last 60 years concerning
the highly parametric equilibrium description of clathrate structures. Molecular (guest− guest …

Clathrate hydrate dynamics with synthetic-and bio-surfactant in porous media: Model formulation and validation

AV Palodkar, AK Jana - Chemical Engineering Science, 2020 - Elsevier
In this contribution, we formulate a model to gain physical insight into the hydration process
in presence of biosurfactant and porous media. This hydrate model addresses several …

A thermodynamic framework to identify apposite refrigerant former for hydrate-based applications

HJ Dongre, A Deshmukh, AK Jana - Scientific Reports, 2022 - nature.com
High latent heat storage capacity with naturally assisted salt rejection makes the clathrate
compounds appropriate for applications towards load management and desalination …

A Deparameterized Clathrate Phase Description Using Crystallography Theory: Validating Guest-Swapping Dynamics in a Gas Hydrate

S Sharma, AK Jana - Energy & Fuels, 2024 - ACS Publications
Parametric description of hydrate phase equilibrium has persisted as a major issue in
clathrate science for more than the last six decades. To explore the long-awaited solution, a …

Gas Hydrate Dynamics with Parameter-Free Clathrate Phase Description: Validation for Hydrate Formation and Dissociation

S Sharma, HJ Dongre, AK Jana - The Journal of Physical …, 2024 - ACS Publications
One of the major challenges involved in clathrate hydrate science that has remained for
more than six decades lies in highly parametric clathrate phase estimation. In this …